[Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄]

Base Information

• Chemical Name: [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄]
• CAS No.: 1162648-53-4
• Molecular Formula: C₈H₂₀N*C₁₄H₁₂ClN₂NiOS₂
• Molecular Weight: 512.791
• Mol file: 1162648-53-4.mol

Synonyms:

Chemical Property of [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄]

There total 3 articles about [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

4-Chloro-benzenethiol anion (35337-68-9) + [Ni2(N-(2-mercaptoethyl)picolinamidate(2-))2] (1162648-50-1) → [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt4] (1162648-53-4)

Guidance literature:

In not given; addn. of 2 equiv. of thiolate deriv. to nickel compd.;

DOI:10.1021/ic9009042

Reference yield: 70.0%

[Ni2(N-2-(mercaptoethyl)picolinamide(-2H))2] (1162648-50-1) + p-Chlorothiophenol (106-54-7) → [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt4] (1162648-53-4)

Guidance literature:

In not given; (N2); using Schlenk techniques; treatment of Ni2(N-2-(mercaptoethyl)picolinamide(-2H))2 with 2 mol-equiv. of ClC6H4SH according to: Gale, E.M.; Patra, A.K.; Harrop, T.C. Inorg. Chem. 2009, 48, 5620;

DOI:10.1021/ic1009187

Reference yield:

[Ni(tert-butylthiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt4] (1162648-56-7) + p-Chlorothiophenol (106-54-7) → [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt4] (1162648-53-4)

Guidance literature:

In not given; treatment of nickel compd. with thiol deriv.;

DOI:10.1021/ic9009042

upstream raw materials:

4-Chloro-benzenethiol anion

[Ni₂(N-(2-mercaptoethyl)picolinamidate^(2-))2]

[Ni(tert-butylthiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄]

p-Chlorothiophenol

Refernces

• 1、 Gale, Eric M.,Narendrapurapu, Beulah S.,Simmonett, Andrew C.,Schaefer, Henry F.,Harrop, Todd C.. "Exploring the effects of H-bonding in synthetic analogues of nickel superoxide dismutase (Ni-SOD): Experimental and theoretical implications for protection of the Ni-SCys bond". . p. 7080 - 7096. Retrieved 2010.