35337-68-9

Basic information

• Product Name: 4-Chloro-benzenethiol anion
• Synonyms: 4-Chloro-benzenethiol anion
• CAS NO: 35337-68-9
• Molecular Weight: 143.617
• Mol File: 35337-68-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 4-Chloro-benzenethiol anion(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Chloro-benzenethiol anion(35337-68-9)
• EPA Substance Registry System: 4-Chloro-benzenethiol anion(35337-68-9)

Safety Data

• Hazardous Substances Data: 35337-68-9(Hazardous Substances Data)

Upstream product

• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 74-90-8 hydrogen cyanide 
• 95062-74-1 S-(4-chlorophenyl) thiocarbamate 
• 123-54-6 acetylacetone 
• 21021-60-3 S-acetyl-4-chlorothiophenol 
• 933-01-7 4-chloro-benzenesulfenyl chloride 
• 108-99-6 3-Methylpyridine 
• 166986-07-8 (4-Chloro-phenylsulfanylmethyl)-methyl-(3-nitro-phenyl)-amine 
• 79108-33-1 p-chlorothiophenyl fluorene-9-carboxylate 
• 64651-83-8 phenyl-thiocarbamic acid (S)-4-chlorophenyl ester 
• 79-24-3 Nitroethane 
• 3309-87-3 S-(4-chlorophenyl) O,O'-dimethyl phosphorothiolate 
• 20114-14-1 (4-chloro-phenyl)-(2,4-dinitro-phenyl)-sulfide 

Downstream Products

• 61266-74-8 2-(4-chloro-phenylsulfanylmethyl)-5-nitro-furan 
• 1162648-53-4 [Ni(para-chlorobenzene thiolato)(N-2-(mercaptoethyl)picolinamide(-2H))][NEt₄] 
• 913545-33-2 2-(4-chlorophenylsulfanyl)pyridinium-N-(4-tolyl)imide 
• 31793-28-9 3,5-Dinitro-2-pyridyl-p-chlorphenylsulfid 
• 137446-81-2 ethyl 3-(4-chlorophenylthio)propanoate 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 3964-18-9 2,3-dimethyl-2,3-dinitrobutane 
• 52755-34-7 1-methyl-1-nitroethyl p-chlorophenyl sulphide 
• 137591-82-3 2-(p-chlorophenylthio)-2-phenyl-1,3-dithiolane 
• 407-16-9 4-chlorophenyl trifluoromethyl sulfide 
• 13343-26-5 phenyl p-chlorophenyl sulfide 
• 64672-75-9 C₂₈H₂₃Cl₃S₄ 

Relevant articles and documents

Reactions of phosphate and phosphorothiolate diesters with nucleophiles: Comparison of transition state structures

A series of methyl aryl phosphorothiolate esters (SP) were synthesized and their reactions with pyridine derivatives were compared to those for methyl aryl phosphate esters (OP). Results show that SP esters react with pyridine nucleophiles via a concerted SN2(P) mechanism. Bronsted analysis suggests that reactions of both SP and OP esters proceed via transition states with dissociative character. The overall similarity of the transition state structures supports the use of phosphorothiolates as substrate analogues to probe mechanisms of enzyme-catalyzed phosphoryl transfer reactions. This journal is The Royal Society of Chemistry.

Kinetics of the Reactions of 2,4-Dinitrophenyl Aryl Sulphides Sulphoxides and Sulphones with Hydroxide Ion in 80 percent (v/v) Ethanol-Water

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The E1cB Mechanism for Thiocarbamate Ester Hydrolysis: Equilibrium and Kinetic Studies

The alkaline hydrolyses of a series of S-aryl thiocarbamate esters have been measured and the mechanism confirmed to be dissociative.Equilibrium constant for the synthesis of thiocarbamates from thiol and isocyanic acid have been obtained for aqueous media using both kinetic and analytical techniques.Hammett and Broensted parameters for the equilibrium reaction indicate that there is less positive effective charge on the sulphur in the thiocarbamate compared with that on the oxygen in the oxygen analogue.Theoretical arguments are advanced to show that the dissociative reactions of simple carbamate anions involve a planar geometry of the paticipating atoms.