(cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron

Base Information

• Chemical Name: (cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron
• CAS No.: 173602-67-0
• Molecular Formula: C₁₆H₁₀FeO₃
• Molecular Weight: 306.101
• Mol file: 173602-67-0.mol

Synonyms:

Chemical Property of (cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron

There total 1 articles about (cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

sodium dicarbonyl(cyclopentadienyl)ferrate + phenylpropyolic acid (637-44-5) → (cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron (173602-67-0)

Guidance literature:

With N-methylmorpholine; isobutyl chloroformate; In tetrahydrofuran; (argon); addn. of N-methylmorpholine and isobutyl chloroformate at 0°C to the acid in THF, stirring (15 min), cooling to -78°C, filtration after 20 min under vac., addn. of the Fe complex, stirring (30 min), warming to r.t. (50 min); after quenching with aq. NH4Cl, concn. (vac.), chromy. (SiO2; Et2O/petroleum ether); elem. anal.;

DOI:10.1002/cber.19961290810

Reference yield: 80.0%

(cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron (173602-67-0) + dimethoxycarbenium hexafluorophosphate (50318-32-6) → dicarbonyl(cyclopentadienyl)[methoxy(phenylethynyl)carbene]iron hexafluorophosphate

Guidance literature:

In dichloromethane; (argon); stirring (room temp., 1 h); pptn. with Et2O, removal of the mother-liquor, washing (Et2O), drying inan argon stream, then in vacuo; elem. anal.;

DOI:10.1002/cber.19961290810

Reference yield: 77.0%

(cyclopentadienyl)dicarbonyl(3-phenylpropynoyl)iron (173602-67-0) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → [Fe(CO)2(C5H5)(COC7H6C6H5)] (181760-94-1)

Guidance literature:

titanium tetrachloride; In dichloromethane; stirring (3 h); diln. with acetone, filtration (Celite), solvent removal (vac.), column chromy. (SiO2; Et2O/petroleum ether), evapn. (rotavapor), storage (-18°C), decantation, drying (vac.); elem. anal.;

DOI:10.1002/cber.19961290913

upstream raw materials:

phenylpropyolic acid

Downstream raw materials:

[Fe(CO)2(C₅H₅)(COC₇H₆C₆H₅)]