[Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl₂]

Base Information

• Chemical Name: [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl₂]
• CAS No.: 1221972-74-2
• Molecular Formula: C₂₅H₂₅Cl₂N₃O₃RuS
• Molecular Weight: 619.534
• Mol file: 1221972-74-2.mol

Synonyms:

Chemical Property of [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl₂]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl₂]

There total 1 articles about [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl₂] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

dichlorotetrakis(dimethylsulfoxide)ruthenium(II) + 4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine (173215-48-0) → [Ru(4'(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)2](2+) (206650-46-6) + [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl2] (1221972-74-2)

Guidance literature:

In methanol; (Ar) soln. Ru complex in MeOH was refluxed for 10 min, ligand was slowlyadded to refluxing soln., mixt. was refluxed for 10 h; mixt. was cooled, ppt. was collected filtration, washed with H2O, MeOH, dried in vac.;

DOI:10.1016/j.poly.2009.12.024

Reference yield: 80.0%

[2,2]bipyridinyl (366-18-7) + [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(DMSO)Cl2] (1221972-74-2) → [Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(2,2'-bipyridine)Cl]Cl (1221972-66-2)

Guidance literature:

In methanol; (N2) suspn. Ru complex and bipyridine in MeOH was refluxed for 1 h; soln. was concd., Et2O was added, ppt. was filered, washed with Et2O, dried in vac., recrystd. from MeCN/Et2O;

DOI:10.1016/j.poly.2009.12.024

upstream raw materials:

4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine

Downstream raw materials:

[Ru(4'-(2,5-dimethoxyphenyl)-2,2':6',2''-terpyridine)(2,2'-bipyridine)Cl]Cl