[5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II)

Base Information

• Chemical Name: [5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II)
• CAS No.: 438457-41-1
• Molecular Formula: C₅₆H₅₅N₅O₂Zn
• Molecular Weight: 895.475
• Mol file: 438457-41-1.mol

Synonyms:

Chemical Property of [5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II)

There total 1 articles about [5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

[5,15-bis(3',5'-di-tert-butylphenyl)-10-bromoporphyrinato]zinc(II) (294183-84-9) + (4-Nitrophenyl)acetylene (937-31-5) → [5,15-bis(3',5'-di-tert-butylphenyl)-10-(4-nitrophenylethynyl)porphyrinato]zinc(II) (438457-41-1)

Guidance literature:

With Pd₂(dibenzylideneacetone)3/PPh₃; CuI; Et₃N/C₅H₅N; In pyridine; triethylamine; toluene; soln. of Pd compd., PPh3, CuI in Et3N was heated at 70°C for 30 min; Zn complex and 4-NO2C6H4CCH were dissolved in toluene/pyridine; catalyst soln. was transferred; mixt. was heated at 80°C for 1h; cooled; filtered through silica plug; chromd. (SiO2, petroleum ether/EtOAc/pyridine, 10/1/0.1); recrystd. (CHCl3/methanol);

DOI:10.1039/b109915a

upstream raw materials:

[5,15-bis(3',5'-di-tert-butylphenyl)-10-bromoporphyrinato]zinc(II)

(4-Nitrophenyl)acetylene