3-(tricyclohexylstannyl)allyl hydroperoxide

Base Information

• Chemical Name: 3-(tricyclohexylstannyl)allyl hydroperoxide
• CAS No.: 144026-93-7
• Molecular Formula: C₂₁H₃₈O₂Sn
• Molecular Weight: 441.242
• Mol file: 144026-93-7.mol

Synonyms:

Chemical Property of 3-(tricyclohexylstannyl)allyl hydroperoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 3-(tricyclohexylstannyl)allyl hydroperoxide

There total 2 articles about 3-(tricyclohexylstannyl)allyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Cy3SnCH2CHCH2 (13121-83-0) + oxygen (80937-33-3) → allylperoxytricyclohexyltin (144026-92-6) + 3-(tricyclohexylstannyl)allyl hydroperoxide (144026-93-7)

Guidance literature:

With tetraphenylporphirin; lithium perchlorate; In diethyl ether; Irradiation (UV/VIS); vigorously stirring of soln. of tricyclohexyl (prop-2-enyl)tin and tetraphenylporphirin in Et2O and 4 mol/dm**-3 soln. of LiClO4 in Et2O under oxygen; irradn. with light from 400 W sodium lamp for 3 h at room temp.; removal of solvent; identification by NMR; Kinetics;

DOI:10.1016/S0022-328X(00)00362-4

Reference yield:

oxygen (7782-44-7) + Cy3SnCH2CHCH2 (13121-83-0) → allylperoxytricyclohexyltin (144026-92-6) + 3-(tricyclohexylstannyl)allyl hydroperoxide (144026-93-7) + 4-tricyclohexylstannyl-1,2-dioxolane (144026-94-8)

Guidance literature:

In chloroform-d1; [D₃]acetonitrile; react. of Sn-compd. with singlet O2 (generated using Rose Bengal and Na lamp) in CDCl3/CD3CN at 15°C; see: H.-S. Dang and A. G. Davies, Tetrahedron Lett., 32 (1991) 1745; J. Chem. Soc., Perkin Trans. 2 (1991) 2011; not isolated, detected by high-resolution NMR-spectroscopy;

DOI:10.1016/0022-328X(92)83265-J

upstream raw materials:

Cy₃SnCH₂CHCH₂

oxygen

oxygen