Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide)

Base Information

• Chemical Name: Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide)
• CAS No.: 632323-00-3
• Molecular Formula: C₄₄H₄₂NP₂Rh
• Molecular Weight: 749.677
• Mol file: 632323-00-3.mol

Synonyms:

Chemical Property of Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide)

There total 1 articles about Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.9%

chlorobis(cyclooctene)rhodium(I) dimer + lithium 2,2'-bis(diphenylphosphino)diphenylamide → Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide) (632323-00-3)

Guidance literature:

In toluene; under Ar; soln. of Li salt of ligand (2 equiv.) in toluene added dropwise to soln. of Rh complex in toluene at 15°C; stirred at room temp. for 90 min; volatiles removed in vac.; dissolved in toluene; concd.; filtered; filtrate dried in vac.;

DOI:10.1016/S0022-328X(03)00776-9

Reference yield: 100.0%

Rh(COE)(2,2'-bis(diphenylphosphino)diphenylamide) (632323-00-3) + carbon monoxide (201230-82-2) → Rh(CO)(2,2'-bis(diphenylphosphino)diphenylamide) (632322-99-7)

Guidance literature:

In benzene; under Ar; Rh complex dissolved in benzene; left under CO (1 atm) at roomtemp. for several h; ppt. collected; elem. anal.;

DOI:10.1016/S0022-328X(03)00776-9

Downstream raw materials:

Rh(CO)(2,2'-bis(diphenylphosphino)diphenylamide)