[Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2

Base Information

Chemical Name:[Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2
CAS No.:1373886-67-9
Molecular Formula:C₁₆₀H₁₆₀Cl₂Ir₂N₄S₁₂
Molecular Weight:2979.2
Hs Code.:

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Chemical Property of [Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2

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Technology Process of [Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2

There total 1 articles about [Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: iridium(III) chloride trihydrate

: 1373886-66-8
4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine

: 1373886-67-9
[Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2

Guidance literature:: In 2-methoxy-ethanol; water; Ir salt and H2O were added to soln. of ligand in 2-methoxyethanol; refluxed under inert atm. for 24 h; cooled to room temp.; filtered; dried; redissolved in CH2Cl2; concd. (vac.); Et2O added under stream of N2; filtered; washed (Et2O);
DOI:10.1021/ic202573y

Reference yield: 51.0%

: 366-18-7
[2,2]bipyridinyl

: sodium hexaflorophosphate

: 1373886-67-9
[Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2

: [Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2(2,2'-bipyridine)]PF₆

Guidance literature:: In methanol; dichloromethane; mixt. of Ir complex and ligand in CH2Cl2/CH3OH (2/1) was refluxed under inert atm. for 6 h; cooled to room temp.; evapd. (vac.); sonicated with Et2O; filtered; washed (Et2O); dissolved in MeOH; NaPF6 was added with stirring; concd.; filtered; washed (H2O); dried (vac.);
DOI:10.1021/ic202573y

Reference yield: 51.0%

: sodium hexaflorophosphate

: 1373886-67-9
[Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2Cl]2

: 14162-93-7
4-nitro-(2,2'-bipyridine)

: [Ir(4-(3',4'-dibutyl-5''-mesityl-2,2':5',2''-terthiophen-5-yl)-2-phenylpyridine)2(4-nitro-2,2'-bipyridine)]PF₆

Guidance literature:: In methanol; dichloromethane; mixt. of Ir complex and ligand in CH2Cl2/CH3OH (2/1) was refluxed under inert atm. for 6 h; cooled to room temp.; evapd. (vac.); sonicated with Et2O; filtered; washed (Et2O); dissolved in MeOH; NaPF6 was added with stirring; concd.; filtered; washed (H2O); dried (vac.);
DOI:10.1021/ic202573y