C₂₄H₂₇ClF₂O₉S₃

Base Information

• Chemical Name: C₂₄H₂₇ClF₂O₉S₃
• CAS No.: 1402428-45-8
• Molecular Formula: C₂₄H₂₇ClF₂O₉S₃
• Molecular Weight: 629.121
• Mol file: 1402428-45-8.mol

Synonyms:

Chemical Property of C₂₄H₂₇ClF₂O₉S₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₄H₂₇ClF₂O₉S₃

There total 9 articles about C₂₄H₂₇ClF₂O₉S₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-[(4-chloro-phenylsulfanyl)-(2,3,6-trifluoro-phenyl)-methyl]-propane-1,3-diol (944950-53-2) → C24H27ClF2O9S3 (1402428-45-8)

Guidance literature:

Multi-step reaction with 13 steps

1: potassium tert-butylate / tetrahydrofuran

2: Dess-Martin periodane / dichloromethane

3: trimethylsilyl trifluoromethanesulfonate

4: boron trifluoride diethyl etherate / dichloromethane

5: oxone / acetone; water

6: triethylamine / dichloromethane

7: potassium tert-butylate / tetrahydrofuran

8: ozone / dichloromethane

9: Resolution of racemate

10: triethylamine

11: potassium hydroxide / ethanol / 70 °C

12: 3-chloro-benzenecarboperoxoic acid / dichloromethane

13: triethylamine / dichloromethane

With oxone; trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; potassium tert-butylate; Dess-Martin periodane; ozone; triethylamine; 3-chloro-benzenecarboperoxoic acid; potassium hydroxide; In tetrahydrofuran; ethanol; dichloromethane; water; acetone;

DOI:10.1016/j.bmcl.2012.11.047

Reference yield:

C23H25ClF2O5S2 (1402428-46-9) → C24H27ClF2O9S3 (1402428-45-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane

2: triethylamine / dichloromethane

With triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1016/j.bmcl.2012.11.047

Reference yield:

C16H13ClF2O2S → C24H27ClF2O9S3 (1402428-45-8)

Guidance literature:

Multi-step reaction with 12 steps

1: Dess-Martin periodane / dichloromethane

2: trimethylsilyl trifluoromethanesulfonate

3: boron trifluoride diethyl etherate / dichloromethane

4: oxone / acetone; water

5: triethylamine / dichloromethane

6: potassium tert-butylate / tetrahydrofuran

7: ozone / dichloromethane

8: Resolution of racemate

9: triethylamine

10: potassium hydroxide / ethanol / 70 °C

11: 3-chloro-benzenecarboperoxoic acid / dichloromethane

12: triethylamine / dichloromethane

With oxone; trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; potassium tert-butylate; Dess-Martin periodane; ozone; triethylamine; 3-chloro-benzenecarboperoxoic acid; potassium hydroxide; In tetrahydrofuran; ethanol; dichloromethane; water; acetone;

DOI:10.1016/j.bmcl.2012.11.047

upstream raw materials:

2-[(4-chloro-phenylsulfanyl)-(2,3,6-trifluoro-phenyl)-methyl]-propane-1,3-diol

C₂₃H₂₅ClF₂O₇S₂

methanesulfonyl chloride

C₂₃H₂₅ClF₂O₅S₂