Technology Process of 1-[3,5-bis(tert-butyl-dimethyl-silanyloxy)-phenyl]-pent-4-en-2-ol
There total 4 articles about 1-[3,5-bis(tert-butyl-dimethyl-silanyloxy)-phenyl]-pent-4-en-2-ol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium hydroxide; dihydrogen peroxide;
In
diethyl ether; water;
at 0 - 20 ℃;
for 12.3333h;
Title compound not separated from byproducts.;
DOI:10.1021/jo071035l
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 85 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / 20 °C
2: diethyl ether / 2 h / -78 °C
3: H2O2; NaOH / diethyl ether; H2O / 12.33 h / 0 - 20 °C
With
sodium hydroxide; dihydrogen peroxide; pyridinium chlorochromate;
In
diethyl ether; dichloromethane; water;
DOI:10.1021/jo071035l
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 91 percent / lithium aluminium hydride / diethyl ether / 3 h / 0 °C
2: 85 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / 20 °C
3: diethyl ether / 2 h / -78 °C
4: H2O2; NaOH / diethyl ether; H2O / 12.33 h / 0 - 20 °C
With
sodium hydroxide; lithium aluminium tetrahydride; dihydrogen peroxide; pyridinium chlorochromate;
In
diethyl ether; dichloromethane; water;
DOI:10.1021/jo071035l
