(PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp

Base Information

• Chemical Name: (PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp
• CAS No.: 289685-71-8
• Molecular Formula: C₅₁H₄₂FeOP₂Pt
• Molecular Weight: 983.768
• Mol file: 289685-71-8.mol

Synonyms:

Chemical Property of (PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp

There total 2 articles about (PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + cyclopentadienyl(3-phenyl-2-propynyl)dicarbonyliron → (PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp (289685-71-8)

Guidance literature:

In tetrahydrofuran; byproducts: P(C6H5)3, CO; (Ar); at reflux temp. for 2 h; cooled; concd. (vac.); crystd. (hexane, -23°C, 12 h); filtered; repeatedly concd./crystd.; elem. anal.;

DOI:10.1021/om000205g

Reference yield:

cyclopentadienyl(3-phenyl-2-propynyl)dicarbonyliron + dicarbonylbis(triphenylphosphine)platinum(0) (15377-00-1) → (PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp (289685-71-8)

Guidance literature:

In tetrahydrofuran; refluxed for 24 h; not isolated; NMR monitoring;

DOI:10.1021/om000205g

Reference yield:

(PPh3)2Pt(μ-η1:η2α,β-C(Ph)=C=CH2)-Fe(CO)Cp (289685-71-8) + carbon monoxide (201230-82-2) → cyclopentadienyl(3-phenyl-2-propynyl)dicarbonyliron + dicarbonylbis(triphenylphosphine)platinum(0) (15377-00-1)

Guidance literature:

In dichloromethane-d2; bubbled CO through soln. complex for 18 h at room temp.; not isolated; NMR monitoring;

DOI:10.1021/om000205g

upstream raw materials:

dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾

tetrakis(triphenylphosphine)platinum

Downstream raw materials:

dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾