[N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)]

Base Information

Chemical Name:[N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)]
CAS No.:443890-19-5
Molecular Formula:C₂₃H₃₅AlN₂
Molecular Weight:366.526
Hs Code.:

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Chemical Property of [N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)]

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Technology Process of [N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)]

There total 2 articles about [N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 443890-22-0
N-(2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldimine

: 75-24-1
trimethylaluminum

: 443890-19-5
[N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)]

Guidance literature:: In hexane; byproducts: CH4; under N2, n-hexane soln. of org. compd. was added to 25 % excess of AlMe3 in 15% n-hexane soln., stirring at room temp. for 16 h; volatiles were removed, residue was extd. with n-hexane, cooling to -32 °C for 16 h, elem. anal.;
DOI:10.1002/1099-0682(200205)2002:5<1060::AID-EJIC1060>3.0.CO;2-5

Reference yield: 80.0%

: 443890-21-9
[N-(2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato]aluminium(III) dichloride

: 75-16-1
methylmagnesium bromide

: 443890-19-5
[N-((2,6-bis(isopropyl)phenyl)-5-tert-butylpyrrolylaldiminato)dimethylaluminium(III)]

Guidance literature:: In diethyl ether; under N2, Schlenk techques; to soln. of Al complex was added MeMgBr at -35°C, mixt. was warmed to room temp., stirred for 24 h; solvent was removed, residue was extd. with pentane, extract was filtered, solvent was removed; elem. anal.;
DOI:10.1016/S0022-328X(03)00555-2