1,2-ferrocenediyl(-PPh₂=C(CHO)-N=C(Me)-)

Base Information

• Chemical Name: 1,2-ferrocenediyl(-PPh₂=C(CHO)-N=C(Me)-)
• CAS No.: 395645-40-6
• Molecular Formula: C₂₆H₂₂FeNOP
• Molecular Weight: 451.288
• Mol file: 395645-40-6.mol

Synonyms:

Chemical Property of 1,2-ferrocenediyl(-PPh₂=C(CHO)-N=C(Me)-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,2-ferrocenediyl(-PPh₂=C(CHO)-N=C(Me)-)

There total 1 articles about 1,2-ferrocenediyl(-PPh₂=C(CHO)-N=C(Me)-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Glyoxal (131543-46-9,107-22-2) + (R)-1-((S)-2-diphenylphosphino)ferrocenylethylamine (172041-83-7,406681-19-4,607389-84-4) → 1,2-ferrocenediyl(-PPh2=C(CHO)-N=C(Me)-) (395645-40-6,394676-61-0)

Guidance literature:

In methanol; water; under N2 atm. to soln. ferrocene in MeOH was added aq. soln. glyoxal, stirred for 5 h at room temp.; soln. was dried over MgSO4, filtered, and evapd. in vacuo, residue was recrystd. from hexane/acetone (4:1); elem. anal.;

DOI:10.1021/om010603z

Reference yield: 95.0%

rhenium(I) pentacarbonyl chloride (14099-01-5) + 1,2-ferrocenediyl(-PPh2=C(CHO)-N=C(Me)-) (395645-40-6,394676-61-0) → C5H5FeC5H3CCH3NCP(C6H5)2COHRe(CO)3Cl (506430-95-1)

Guidance literature:

In tetrahydrofuran; soln. of Fe- and Re-complexes in THF was heated under reflux for 5 h under N2; solvent was removed under vac., chromd. on silica gel with Et2O/MeOH, recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1021/om020929n

Reference yield: 92.0%

tungsten hexacarbonyl (14040-11-0) + 1,2-ferrocenediyl(-PPh2=C(CHO)-N=C(Me)-) (395645-40-6,394676-61-0) → C5H5FeC5H3CCH3NCP(C6H5)2COHW(CO)4

Guidance literature:

In tetrahydrofuran; toluene; mixt. of Fe- and W-complexes in THF and toluene was stirred at 90°C for 3 h under N2; chromd. on silica gel with MeOH and Et2O, solvent was removed, recrystd.from CH2Cl2-Et2O; elem. anal.;

DOI:10.1021/om020929n

upstream raw materials:

Glyoxal

(R)-1-((S)-2-diphenylphosphino)ferrocenylethylamine

Downstream raw materials:

C₅H₅FeC₅H₃CCH₃NCP(C₆H₅)2COHPdC₃H₅⁽¹⁺⁾*BF₄^(1-)=C₅H₅FeC₅H₃CCH₃NCP(C₆H₅)2COHPdC₃H₅BF₄

C₅H₅FeC₅H₃CCH₃NCP(C₆H₅)2COHMn(CO)3Br

C₅H₅FeC₅H₃CCH₃NCP(C₆H₅)2COHRe(CO)3Cl