(AuS₂P(C₆H₅)OC₂H₃CH₂)2

Base Information

• Chemical Name: (AuS₂P(C₆H₅)OC₂H₃CH₂)2
• CAS No.: 259233-63-1
• Molecular Formula: C₁₈H₂₀Au₂O₂P₂S₄
• Molecular Weight: 852.5
• Mol file: 259233-63-1.mol

Synonyms:

Chemical Property of (AuS₂P(C₆H₅)OC₂H₃CH₂)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (AuS₂P(C₆H₅)OC₂H₃CH₂)2

There total 3 articles about (AuS₂P(C₆H₅)OC₂H₃CH₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + NH4(1+)*S2PC6H5(OCH2CHCH2)(1-)=(NH4)(S2PC6H5(OCH2CHCH2)) (259174-06-6) → (AuS2P(C6H5)OC2H3CH2)2 (259233-63-1,460711-24-4)

Guidance literature:

In tetrahydrofuran; byproducts: NH4Cl; Au-complex in THF was added to soln. of dithiophosphate in THF under inert atm., the mixt. was stirred for 40 min; the solvent was removed in vac., extd. with CH2Cl2, filtered through anhydrous MgSO4, evapd. under reduced pressure, washed with ether, dried under vac.;

DOI:10.1021/ic0201856

Reference yield:

(AuS2P(C6H5)OC2H3CH2)2 (259233-63-1,460711-24-4) → (AuS2P(C6H5)OC2H3CH2)2 (460711-24-4,259233-63-1)

Guidance literature:

In chloroform-d1; CDCl3, room temp.; not sepd., detected by NMR spectra;

DOI:10.1021/ic0201856

Reference yield:

{Au(tetrahydrothiophene)Cl} (39929-21-0) + NH4(1+)*S2PC6H5(OCH2CHCH2)(1-)=(NH4)(S2PC6H5(OCH2CHCH2)) (259174-06-6) → (AuS2PC6H5(OCH2CHCH2))2 (259233-63-1,460711-24-4)

Guidance literature:

In tetrahydrofuran; byproducts: NH4Cl; Schlenk tube charged with organic salt, placed under vac. for 30 min, then dissolved in THF and Au salt added in one portion at room temp., stirred for 40 min, solvent removed in vac.; extd. with CH2Cl2, filtered through anhydrous MgSO4, filtrate evapd. invac., washed with ether, dried under vac. for 1 h;

DOI:10.1016/S0022-2860(99)00231-8

upstream raw materials:

{Au(tetrahydrothiophene)Cl}

NH₄⁽¹⁺⁾*S₂PC₆H₅(OCH₂CHCH₂)^(1-)=(NH₄)(S₂PC₆H₅(OCH₂CHCH₂))

(tetrahydrothiophene)gold(I) chloride

(AuS₂P(C₆H₅)OC₂H₃CH₂)2

Downstream raw materials:

(AuS₂P(C₆H₅)OC₂H₃CH₂)2