[(o-carboranylphosphinothiolato)Ir(CO)]2

Base Information

Chemical Name:[(o-carboranylphosphinothiolato)Ir(CO)]2
CAS No.:287400-36-6
Molecular Formula:C₃₀H₄₀B₂₀Ir₂O₂P₂S₂
Molecular Weight:1159.39
Hs Code.:

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Chemical Property of [(o-carboranylphosphinothiolato)Ir(CO)]2

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Technology Process of [(o-carboranylphosphinothiolato)Ir(CO)]2

There total 1 articles about [(o-carboranylphosphinothiolato)Ir(CO)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: [{Ir(μ-Cl)(CO)2}2]

: 287400-39-9
closo-1-(diphenylphosphino)-2-(lithiumthiolato)-o-carborane

: 287400-36-6
[(o-carboranylphosphinothiolato)Ir(CO)]2

Guidance literature:: In tetrahydrofuran; (N2 or Ar); using Schlenk techniques; dissolving of LiS(C2B10H10PPh2) (1equiv.) in dry THF, cooling to -10°C, addn. of (IrCl(CO)2)2 (1 e quiv.) with stirring over 30 min, warming to room temp.; filtration in air, removal of solvent under reduced pressure, chromy. with CH2Cl2 as eluent, removal of solvent;

Reference yield: 75.0%

: 287400-36-6
[(o-carboranylphosphinothiolato)Ir(CO)]2

: 554-70-1
triethylphosphine

: 287400-38-8
trans-[Ir(CO)(SC₂B₁₀H₁₀PPh₂)(PEt₃)]

Guidance literature:: In toluene; (N2 or Ar); using Schlenk techniques; treatment of soln. of (Ir(SC2B10H10PPh2)(CO))2 (1 equiv.) in toluene with PEt3 (3 equiv.) at room temp. for 1 h; removal of volatile substances in vac., extn. with CH2Cl2, addn. of hexane, crystn., elem. anal.;