dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III)

Base Information

Chemical Name:dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III)
CAS No.:1042659-40-4
Molecular Formula:C₄₇H₃₈Cl₂IrNP₂
Molecular Weight:941.899
Hs Code.:

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Chemical Property of dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III)

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Technology Process of dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III)

There total 1 articles about dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 1008-89-5
2-phenylpyridine

: iridium(III) chloride hydrate

: 603-35-0
triphenylphosphine

: 1042659-40-4
dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III)

Guidance literature:: In 2-ethoxy-ethanol; water; byproducts: H2O; under N2; mixt. of IrCl3*nH2O, PPh3 and 2-phenylpyridine in 2-ethoxyethanol and H2O refluxed for 12 h; cooled to 25°C; filtered; ppt. washed with MeOH and CH2Cl2; dried under vac.;
DOI:10.1021/ic800376e

Reference yield: 95.0%

: 1042659-40-4
dichloro(2-phenylpyridinato)bis(triphenylphosphine)iridium(III)

: 2923-28-6
silver trifluoromethanesulfonate

: 75-05-8,26809-02-9
acetonitrile

: 1042659-42-6
acetonitrile(chloro)(2-phenylpyridinato)bis(triphenylphosphine)iridium(III) triflate

Guidance literature:: In chloroform; acetonitrile; byproducts: AgCl; under N2; mixt. of Ir complex and Ag triflate in CHCl3-MeCN stirred at 25°C for 2 h; filtered; MeCN added to filtrate; stirred for 2 h; n-pentane added; filtered; ppt. washed with n-pentane; dried under vac.;elem. anal.;
DOI:10.1021/ic800376e