η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride

Base Information

• Chemical Name: η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride
• CAS No.: 78670-95-8
• Molecular Formula: BF₄*C₂₈H₂₂MnNO₂P
• Molecular Weight: 577.205
• Mol file: 78670-95-8.mol

Synonyms:

Chemical Property of η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride

There total 1 articles about η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

nitronium tetrafluoborate + (η5-indenyl)Mn(CO)2PPh3 (31871-85-9) → η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride (78670-95-8)

Guidance literature:

In nitromethane; dichloromethane; under inert atmosphere, NO2BF4 added with stirrig (-10°C) to soln. of C9H7Mn(CO)2PPh3, mixed 1 h at 20°C; solvent removed in vac.; twice washed (ether), recrystd. (alcohol, CH2Cl2/hexane);

DOI:10.1007/BF00955267

Reference yield: 43.0%

η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride (78670-95-8) → iododinitrosylbis(triphenylphosphine)manganese

Guidance literature:

With potassium iodide; In tetrahydrofuran; under inert atmosphere, mixed for 84 h at 20°C; residence for 10d at 20°C; solvent removed in vac., chromd. (Al2O3); elem. anal.;

DOI:10.1007/BF00955267

Reference yield: 24.0%

η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride (78670-95-8) → (((C6H5)3P)2(NO)2Mn)Br

Guidance literature:

With potassium bromide; In tetrahydrofuran; under inert atmosphere, mixed for 5.5 h at 20°C; solvent evapd. in vac., extd. (toluene), evapd., washed several times (pentane);

DOI:10.1007/BF00955267

upstream raw materials:

(η5-indenyl)Mn(CO)2PPh3

Downstream raw materials:

cyanodinitrosylbis(triphenylphosphine)manganese