(η5-indenyl)Mn(CO)2PPh3

Base Information

Chemical Name:(η5-indenyl)Mn(CO)2PPh3
CAS No.:31871-85-9
Molecular Formula:C₂₉H₂₂MnO₂P
Molecular Weight:488.404
Hs Code.:

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Chemical Property of (η5-indenyl)Mn(CO)2PPh3

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Technology Process of (η5-indenyl)Mn(CO)2PPh3

There total 2 articles about (η5-indenyl)Mn(CO)2PPh3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 11.0%

: 373389-88-9
[(η6-indane)Mn(CO)3][BF4]

: 603-35-0
triphenylphosphine

: 31871-85-9
(η5-indenyl)Mn(CO)2PPh3

Guidance literature:: With tert-BuOK; In tetrahydrofuran; (N2) mixt. Mn complex, t-BuOK and PPh3 in THF was maintained at 40°C for 20.5 h; solvent was removed in vacuo;
DOI:10.1139/V08-122

Reference yield:

: [(η(5)-indenyl)Mn(CO)3]

: 31871-85-9
(η5-indenyl)Mn(CO)2PPh3

Guidance literature:: With triphenylphosphine; In decalin; byproducts: CO; 130°C; not isolated, reaction followed by IR spectroscopy; Kinetics;
DOI:10.1039/c39830001208

Reference yield: 55.0%

: nitronium tetrafluoborate

: 31871-85-9
(η5-indenyl)Mn(CO)2PPh3

: 78670-95-8
η5-indenyltriphenylphosphinecarbonylnitrosylmanganese borofluoride

Guidance literature:: In nitromethane; dichloromethane; under inert atmosphere, NO2BF4 added with stirrig (-10°C) to soln. of C9H7Mn(CO)2PPh3, mixed 1 h at 20°C; solvent removed in vac.; twice washed (ether), recrystd. (alcohol, CH2Cl2/hexane);
DOI:10.1007/BF00955267