Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-)

Base Information

Chemical Name:Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-)
CAS No.:49655-08-5
Molecular Formula:C₂₃H₁₈FeO₄P*Li
Molecular Weight:452.155
Hs Code.:

Li<sup>(1+)</sup>*P(C<sub>6</sub>H<sub>5</sub>)3(CO)3FeC(CH<sub>3</sub>)O<sup>(1-)</sup>

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-)

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Technology Process of Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-)

There total 1 articles about Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 35679-07-3
[Fe(CO)4(triphenylphosphane)]

: 917-54-4
methyllithium

: 49655-08-5
Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-)

Guidance literature:: In tetrahydrofuran; diethyl ether; To a soln. of complex in THF at -78°C was added a soln. of MeLi in ether, the soln. was warmed to 0°C and stirred for 5 min (inert atm.);; evapd. in vac. at 0°C, dissolved in ether, concd. under vac.; ppt. was filtered, washed with cold ether and vac.-dried at 1E-4 torr for 16 h;;
DOI:10.1021/om00087a001

Reference yield: 48.0%

: 2857-97-8
trimethylsilyl bromide

: 49655-08-5
Li⁽¹⁺⁾*P(C₆H₅)3(CO)3FeC(CH₃)O^(1-)

: 90195-61-2
P(C₆H₅)3(CO)3FeC(CH₃)OSi(CH₃)3

Guidance literature:: In dichloromethane; Me3SiBr was added to a suspn. of complex in CH2Cl2 at -78°C, warmed to -15°C, stirred for 30 min; (inert atm.);; evapd., extd. with hexane-benzene at 25°C; evapd., extd. with hexane, cooled to -95°C; ppt. was filtered and vac.-dried at 1E-4 torr;;
DOI:10.1021/om00087a001