3,3-dibenzyl-1,2-diferrocenylcyclopropene

Base Information

Chemical Name:3,3-dibenzyl-1,2-diferrocenylcyclopropene
CAS No.:686744-66-1
Molecular Formula:C₃₇H₃₂Fe₂
Molecular Weight:588.355
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3,3-dibenzyl-1,2-diferrocenylcyclopropene

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Technology Process of 3,3-dibenzyl-1,2-diferrocenylcyclopropene

There total 2 articles about 3,3-dibenzyl-1,2-diferrocenylcyclopropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

: 56551-49-6
2,3-diferrocenylcyclopropenone

: 7732-18-5
water

: 6921-34-2
benzylmagnesium chloride

: 686744-90-1,686744-69-4
3,4-diferrocenyl-1,5-diphenylpentan-2-one

: 686744-66-1
3,3-dibenzyl-1,2-diferrocenylcyclopropene

Guidance literature:: In diethyl ether; benzene; (inert atm.); addn. of a soln. of magnesium compd. in Et2O to a soln. ofiron complex in benzene, stirring for 3 h at 20°C; addn. of water, sepn., washing org. layer with water, evapn., chromy. (Al2O3, hexane/Et2O 2:1); elem. anal.;
DOI:10.1039/b307408k

Reference yield: 20.0%

: 56551-49-6
2,3-diferrocenylcyclopropenone

: 7732-18-5
water

: 6921-34-2
benzylmagnesium chloride

: 686744-90-1,686744-69-4
3,4-diferrocenyl-1,5-diphenylpentan-2-one

: 686744-66-1
3,3-dibenzyl-1,2-diferrocenylcyclopropene

: cis-4-phenyl-1,2-diferrocenylbut-1-en-3-one

: 813462-38-3
2-hydroxy-3-oxo-1,2-diferrocenyl-1,2,3,4-tetrahydronaphthalene

: 4-(3-phenyl-1-ferrocenyl-2-oxopropyl)-2,3,4-triferrocenylcyclobutenone

Guidance literature:: In diethyl ether; benzene; soln. of PhCH2MgCl in Et2O added dropwise to soln. of Fe complex in anhyd. benzene; stirred at 20°C for 3 h; water added; org. layer sepd.; washed with water; benzene evapd. under vac.; chromy. (Al2O3, hexane/Et2O (2/1)); mixt. of two diastereomers of 1,5-diphenyl-3,4-diferrocenylpentan-2-one (3:1) obtained; elem. anal.;
DOI:10.1023/B:RUCB.0000037852.21475.1a

Reference yield: 60.0%

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 686744-66-1
3,3-dibenzyl-1,2-diferrocenylcyclopropene

: 686744-76-3
(C₅H₅FeC₅H₄)2C₃H(CH₂C₆H₅)2⁽¹⁺⁾*BF₄^(1-)=(C₅H₅FeC₅H₄)2C₃H(CH₂C₆H₅)2BF₄

Guidance literature:: In diethyl ether; (N2); dropwise addn. of acid to a soln. of iron complex in Et2O at -50°C, stirring for 15 min at -50°C; decantation, washing with cold Et2O, drying in vac. with cooling;
DOI:10.1039/b307408k