Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)

Base Information

Chemical Name:Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)
CAS No.:329358-28-3
Molecular Formula:C₃₈H₂₇NO₈Os₃P₂S
Molecular Weight:1290.25
Hs Code.:

Synonyms:

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Chemical Property of Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)

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Technology Process of Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)

There total 4 articles about Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 2637-34-5,73018-10-7
2-Sulfanylpyridine

: [(μ-H)(CO)8(Ph2PCH2P(Ph)C6H4)]

: 329358-28-3
Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)

: [H(H)Os₃(CO)8(C₅H₄NS)((C₆H₅)2PCH₂P(C₆H₅)C₆H₄)]*CH₂Cl₂

Guidance literature:: In dichloromethane; (N2); standard Schlenk technique; pySH (2 equiv.) added to soln. of Os complex in CH2Cl2; stirred at room temp. for 72 h; solvent removed under reduced pressure; chromd. by TLC (SiO2, hexane/CH2Cl2, 7/3); recrystd. (hexane/CH2Cl2, -20°C); elem. anal.;
DOI:10.1016/S0022-328X(00)00696-3

Reference yield: 38.0%

: [(μ-H)(CO)8(Ph2PCH2P(Ph)C6H4)]

: 20637-89-2
pyridin2-2-thiolate-triphenyltin

: 329358-28-3
Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)

: Os3(CO)7(triphenyltin)(μ-pyridine-2-thiolate)(μ-H)(μ-Ph2PCH2PhC6H4)

Guidance literature:: In toluene; (N2), soln. of Os complex and ligand (1:2) in toluene refluxed for 2.5 h; evapd.(vac.), chromy.(silica gel - hexane/CH2Cl2 1:1 v/v), recrydtd.(hexane/CH2Cl2) at 4°C, elem. anal.;
DOI:10.1016/j.jorganchem.2010.11.022

Reference yield: 20.0%

: 2637-34-5,73018-10-7
2-Sulfanylpyridine

: [(μ-H)(CO)8(Ph2PCH2P(Ph)C6H4)]

: 329358-28-3
Os3(CO)8(μ-pyridine-2-thiolate)(μ-H)(μ-dppm)

: 329358-31-8
[Os₃(CO)8(C₅H₄NS)((C₆H₅)2PCH₂P(C₆H₅)C₆H₄)]

: [H(H)Os₃(CO)8(C₅H₄NS)((C₆H₅)2PCH₂P(C₆H₅)C₆H₄)]*CH₂Cl₂

Guidance literature:: In benzene; (N2); standard Schlenk technique; pySH added to soln. of Os complex in benzene; refluxed for 3 h; solvent removed under reduced pressure; chromd. by TLC (SiO2, hexane/CH2Cl2, 7/3); recrystd. (hexane/CH2Cl2, -20°C); elem. anal.;
DOI:10.1016/S0022-328X(00)00696-3