[Pt₂Cl₂(2-CMe₂C₆H₃(4-OMe)P(C₆H₄(2-iPr)(4-OMe))2)2]

Base Information

• Chemical Name: [Pt₂Cl₂(2-CMe₂C₆H₃(4-OMe)P(C₆H₄(2-iPr)(4-OMe))2)2]
• CAS No.: 849192-00-3
• Molecular Formula: C₆₀H₇₆Cl₂O₆P₂Pt₂
• Molecular Weight: 1416.27
• Mol file: 849192-00-3.mol

Synonyms:

Chemical Property of [Pt₂Cl₂(2-CMe₂C₆H₃(4-OMe)P(C₆H₄(2-iPr)(4-OMe))2)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt₂Cl₂(2-CMe₂C₆H₃(4-OMe)P(C₆H₄(2-iPr)(4-OMe))2)2]

There total 1 articles about [Pt₂Cl₂(2-CMe₂C₆H₃(4-OMe)P(C₆H₄(2-iPr)(4-OMe))2)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

tri-(o-isopropyl-p-methoxyphenyl)phosphine (849192-02-5) + dichlorobis(trimethylacetonitrile)platinum(II) (41884-65-5,60479-35-8,51014-04-1) → trans-[Pt2Cl2((tri-(o-isopropyl-p-methoxyphenyl)phosphine)-H)2] (849192-00-3)

Guidance literature:

In toluene; under N2; ligand (0.107 mmol) and Pt-contg. compd. (0.053 mmol) were dissolved in toluene, heated at reflux for 28 h and cooled to room temp.; hexane was added; cooling in a freezer; the solid was filtered off, washed with cold hexane and dried in vac.;

DOI:10.1039/b416525j

Reference yield: 67.0%

sulfuryl dichloride (7791-25-5) + [Pt2Cl2(2-CMe2C6H3(4-OMe)P(C6H4(2-iPr)(4-OMe))2)2] (849192-00-3) → [PtCl2(2-CH2CMeC6H3(4-OMe)P(C6H2(4-OMe)(5-Cl)(2-iPr))2)] (1073295-96-1)

Guidance literature:

In toluene; (N2); addn. of thionylchloride to toluene suspn. of platinum compd., stirring for 4 h; evapn., washing with hexane, elem. anal.;

DOI:10.1021/om800382m

Reference yield: 45.0%

[Pt2Cl2(2-CMe2C6H3(4-OMe)P(C6H4(2-iPr)(4-OMe))2)2] (849192-00-3) + 1,1,2,2-tetrachloroethane (79-34-5) → [PtCl2(2-CH2CMeC6H3(4-OMe)P(C6H3(2-iPr)(4-OMe))2)] (1073295-97-2)

Guidance literature:

In further solvent(s); (N2); refluxing suspn. of platinum compd. in tetrachloroethane for 4 h; evapn., dissolving in CDCl3, filtration, evapn., elem. anal.;

DOI:10.1021/om800382m

upstream raw materials:

tri-(o-isopropyl-p-methoxyphenyl)phosphine

dichlorobis(trimethylacetonitrile)platinum(II)

Downstream raw materials:

[PtCl₂(2-CH₂CMeC₆H₃(4-OMe)P(C₆H₃(2-iPr)(4-OMe))2)]

[PtCl₂(2-CH₂CMeC₆H₃(4-OMe)P(C₆H₂(4-OMe)(5-Cl)(2-iPr))2)]