79-34-5

Basic information

• Product Name: 1,1,2,2-Tetrach loroethane
• Synonyms: 1,1,2,2-TCE;1,1,2,2-Tetrachlorethane;Acetylene tetrachloride;Bonoform;Cellon;F 130;F 130 (halocarbon);NSC 60912;Tetrachloroethane;s-Tetrachloroethane;sym-Tetrachloroethane;1,1,2,2- Tetrachloroethane
• CAS NO: 79-34-5
• Molecular Formula: C₂H₂Cl₄
• Molecular Weight: 167.84928
• EINECS: 201-197-8
• Mol File: 79-34-5.mol
• Article Data: 34

Chemical Properties

• Melting Point: -43℃
• Boiling Point: 142 °C at 760 mmHg
• Flash Point: 42.6 °C
• Appearance: colourless to light yellow liquid
• Density: 1.556 g/cm³
• Vapor Density: 5.8 (vs air)
• Vapor Pressure: 10.9mmHg at 25°C
• Refractive Index: 1.484
• Water Solubility: 0.3 g/100 mL (25℃)
• CAS DataBase Reference: 1,1,2,2-Tetrach loroethane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,2,2-Tetrach loroethane(79-34-5)
• EPA Substance Registry System: 1,1,2,2-Tetrach loroethane(79-34-5)

Safety Data

• Hazard Codes: T+:Very toxic
• Statements: R26/27:; R51/53:
• Safety Statements: S38:; S45:; S61:
• RIDADR: 1702
• HazardClass: 6.1
• PackingGroup: II
• Hazardous Substances Data: 79-34-5(Hazardous Substances Data)

Usage

General Description

1,1,2,2-Tetrachloroethane is a clear, heavy, non-flammable liquid chemical compound with a sweet odor, often used in the industrial sector. The formulation is derived from hydrocarbons, specifically, two carbon atoms and four chlorine atoms (C2H2Cl4). It is primarily utilized as an intermediate in the production of other chemicals and as a solvent in the manufacturing and pharmaceutical industries. Its density is heavier than water and it is insoluble, therefore it sinks into water. Despite its utility, it poses a potential health risk as it is considered toxic and can cause harm to the liver, kidney, and lungs when inhaled, ingested, or even upon skin contact.

InChI:InChI=1/C2H2Cl4/c3-1-2(4,5)6/h1H2

Synthetic route

trans-1,2-dichloroethylene (156-60-5) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With 2,3-dimethylbutane In benzene at 20℃; Irradiation;	94%
With chlorine at 80 - 95℃; unter Ausschluss von Sauerstoff;

C11H16Cl10NO3P (76107-35-2) → bis(2,2,2-trichloroethyl) piperidinophosphonate (76078-37-0) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 180℃; under 0.03 Torr;	A 89% B 93%

C10H14Cl10NO4P (76078-34-7) → bis(2,2,2-trichloroethyl) morpholinophosphonate (76078-38-1) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 180℃; under 0.03 Torr;	A 87% B 93%

N,N-Dichlorobenzenesulfonamide (473-29-0) + 1,2-Dichloroethylene (540-59-0) → benzenesulfonamide (98-10-2) + N-(2,2-dichloroethylidene)benzenesulfonamide (113791-97-2) + N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide (79054-58-3) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 47 - 55℃; for 10h; Irradiation; Further byproducts given. Yields of byproduct given;	A n/a B n/a C 80.7% D n/a

(2-Chlor-vinyl)-dimethyl-chlorsilan (18142-52-4) → 1,2-Dichloroethylene (540-59-0) + dimethylsilicon dichloride (75-78-5) + Chloro-dimethyl-(1,2,2-trichloro-ethyl)-silane (176102-95-7) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine for 5h; Further byproducts given;	A 5% B 6% C 70% D 2%

N,N-Dichlorobenzenesulfonamide (473-29-0) + 1,2-Dichloroethylene (540-59-0) → 1,1,2,2-tetrachloroethylene (127-18-4) + Trichloroethylene (79-01-6) + N-(2,2,2-trichloroethylidene)benzenesulfonamide (55596-11-7) + N-(2,2-dichloroethylidene)benzenesulfonamide (113791-97-2) + N-{2,2-dichloro-1-[(phenylsulfonyl)amino]ethyl}benzenesulfonamide (79054-58-3) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;	A n/a B n/a C n/a D n/a E 54.1% F n/a

1,2-Dichloroethylene (540-59-0) + N,N-dichloro-4-chlorobenzenesulfonamide (17260-65-0) → N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide (113791-98-3) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
for 4h; Irradiation;	A 50% B n/a

N,N-Dichlorobenzenesulfonamide (473-29-0) + 1,2-Dichloroethylene (540-59-0) → N-(2,2-dichloroethylidene)benzenesulfonamide (113791-97-2) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
for 4h; Irradiation;	A 45% B n/a

β-chlorovinyltrimethylsilane (35802-68-7) → chloro-trimethyl-silane (75-77-4) + 1,2-Dichloroethylene (540-59-0) + Trimethyl-(1,2,2-trichloro-ethyl)-silane + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine for 5h; Further byproducts given;	A 10% B 7% C 45% D 3%

β-chlorovinyltrimethylsilane (35802-68-7) → 1,2-Dichloroethylene (540-59-0) + Trimethyl-(pentachlorethyl)-silan (18163-49-0) + Trimethyl-(1,2,2-trichloro-ethyl)-silane + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine for 5h; Further byproducts given;	A 7% B 14% C 45% D 3%

N,N-dichloro-p-toluenesulfonamide (473-34-7) + 1,2-Dichloroethylene (540-59-0) → N-(2,2,2-trichloroethyliden)-p-toluenesulfonamide (51608-61-8, 13707-44-3) + Trichloroethylene (79-01-6) + N-(2,2-dichloro-1-{[(4-methylphenyl)sulfonyl]amino}ethyl)-4-methylbenzenesulfonamide (92962-02-2) + toluene-4-sulfonamide (70-55-3) + N-[2,2-Dichloro-eth-(E)-ylidene]-4-methyl-benzenesulfonamide (113792-00-0) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;	A n/a B n/a C 44.1% D n/a E n/a F n/a

pentachloroethane (76-01-7) → Trichloroethylene (79-01-6) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With hexacarbonyl molybdenum at 140℃; for 3h; further reagent Fe(CO)5;	A 42% B 23%
With iron pentacarbonyl at 140℃; for 3h; further reagent Mo(CO)6;	A 27% B 23%

1,2-Dichloroethylene (540-59-0) + N,N-dichloro-4-chlorobenzenesulfonamide (17260-65-0) → 1,1,2,2-tetrachloroethylene (127-18-4) + 4-Chlorobenzenesulfonamide (98-64-6) + N-(2,2,2-trichloroethylidene)-4-chlorobenzenesulfonamide (81924-15-4) + N-(2,2-dichloroethylidene)-p-chlorobenzenesulfonamide (113791-98-3) + N-<2,2-dichloro-1-(N-p-chlorobenzenesulfonamido)ethyl>-p-chlorobenzenesulfonamide (113792-01-1) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 55℃; for 22h; Product distribution; other time, other temperature, other initiator;	A n/a B n/a C n/a D n/a E 40.4% F n/a

4-Phenylbutyric acid (1821-12-1) → Propylbenzene (103-65-1) + 1,6-diphenylhexane (1087-49-6) + 1,3-difluoro-1-phenylpropane + 1-fluoro-3-phenylpropane (2038-62-2) + 1-fluoro-1-phenylpropane (19031-70-0) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With xenon fluoride In dichloromethane at 20℃; for 14 - 18h; Inert atmosphere;	A 18% B 11% C 12% D 32% E 6% F 14%

chloroform (67-66-3) + aniline (62-53-3) → dichloromethane (75-09-2) + phenyl isocyanate (1197040-29-1) + Azobenzene (1227476-15-4) + N-phenylphenylene-1,4-diamine (101-54-2) + N-phenyl-1,2-benzenediamine (534-85-0) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 15℃; for 24h; Product distribution; Mechanism; Irradiation;	A n/a B 30.2% C 12.5% D 10.5% E 18.4% F n/a

cis-1,2-Dichloroethylene (156-59-2) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine at 80 - 95℃; unter Ausschluss von Sauerstoff;
With sulfuryl dichloride; dibenzoyl peroxide

diethyl ether (60-29-7) + hexachloroethane (67-72-1) + ethylmagnesium bromide (925-90-6) → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1,1,2-tetrachoroethane (630-20-6) + pentachloroethane (76-01-7) + 1,1,2,2-tetrachloroethane (79-34-5)

diethyl ether (60-29-7) + hexachloroethane (67-72-1) + phenylmagnesium bromide → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1,1,2-tetrachoroethane (630-20-6) + pentachloroethane (76-01-7) + 1,1,2,2-tetrachloroethane (79-34-5)

1,2-Dichloroethylene (540-59-0) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine im UV-Licht;

ethane (74-84-0) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With hydrogenchloride; kieselguhr; air; copper dichloride

chloroform (67-66-3) → tetrachloromethane (56-23-5) + 1,1,2,2-tetrachloroethylene (127-18-4) + pentachloroethane (76-01-7) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
beim Durchgang des elektrischen Lichtbogens; weitere Produkten: Hexachloraethan, Hexachlorbenzol, HCl und Kohle;

1,1,2-trichloro-2-iodo-ethane (16452-89-4) → 1,2-Dichloroethylene (540-59-0) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
bei der Destillation;

Trichloroethylene (79-01-6) → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1,2,4,4-pentachloro-1,3-butadiene (21400-41-9) + 1,1,1,2-tetrachoroethane (630-20-6) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
at 200 - 250℃; under 934095 Torr; Produkt5:Pentachloraethan.Pyrolysis;

2,2-dichloroacetaldehyde (79-02-7) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With phosphorus pentachloride

1-chloro-2-dichloroiodanyl-ethene (18964-25-5) → 1,1,2,2-tetrachloroethane (79-34-5)

1,2-dichloro-ethane (107-06-2) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With aluminium trichloride at 70 - 75℃; Einleiten Chlor und gleichzeitig Acetylen,auschliessend jede Spur von Luft;

diethyl ether (60-29-7) + hexachloroethane (67-72-1) + para-methylphenylmagnesium bromide (4294-57-9) → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1,1,2-tetrachoroethane (630-20-6) + pentachloroethane (76-01-7) + 1,1,2,2-tetrachloroethane (79-34-5)

diethyl ether (60-29-7) + hexachloroethane (67-72-1) + 1-naphthylmagnesiumbromide (703-55-9) → 1,1,2,2-tetrachloroethylene (127-18-4) + 1,1,1,2-tetrachoroethane (630-20-6) + pentachloroethane (76-01-7) + 1,1,2,2-tetrachloroethane (79-34-5)

acetylene (74-86-2) → 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine
With chlorine; 1,1,2,2-tetrachloroethane
With chlorine; iron(III) chloride

acetylene (74-86-2) → 1,1-Dichloroethylene (75-35-4) + 1,1,2,2-tetrachloroethane (79-34-5)

Conditions	Yield
With chlorine; iron(III) chloride; 1,1,2,2-tetrachloroethane at 135℃;

copper hydroxide (20427-59-2) + 1,5-diamino-3-azapentane (111-40-0) + 1,1,2,2-tetrachloroethane (79-34-5) → Cu2(C12H26N6Cl4)(H2O)2(4+)*4Cl(1-)=[Cu2(C12H26N6Cl4)(H2O)2]Cl4

Conditions

Yield

In water; butan-1-ol mixing Cu(OH)2 and amine in n-BuOH, stirring (room temp., 10 min), addn.of C2H2Cl4, refluxing (8 h; pptn.), addn. of water, stirring, sepd. of aq. layer, filtration of aq. layer, washing (n-BuOH), crystn. on volume reduction and standing (refrigerator); treating of crude product with mixt. of ether/benzene (1/1) on filtration paper, washing (ether), drying (reduced pressure); elem. anal.;

95.6%

copper hydroxide (20427-59-2) + Trimethylenediamine (109-76-2) + 1,1,2,2-tetrachloroethane (79-34-5) → Cu2(C10H20N4Cl4)(H2O)4(4+)*4Cl(1-)*8H2O = [Cu2(C10H20N4Cl4)(H2O)4]Cl4*8H2O

Conditions	Yield
In water; butan-1-ol refluxing in butanol (10 h), extraction (water); pptn. from aq. phase (concn., cooling); elem. anal.;	95%

1,1,2,2-tetrachloroethane (79-34-5) → 1,1,1-trifluoro-2-chloroethane (75-88-7)

Conditions	Yield
With hydrogen fluoride; antimonypentachloride at 80 - 90℃; Autoclave;	92.3%
With hydrogen fluoride; antimonypentachloride; chlorine at 120℃;

C145H138O24*CHCl3 + 1,1,2,2-tetrachloroethane (79-34-5) → C145H138O24*C2H2Cl4

Conditions	Yield
at 140℃; for 72h;	92%

C148H136O24*CHCl3 + 1,1,2,2-tetrachloroethane (79-34-5) → C148H136O24*C2H2Cl4

Conditions	Yield
at 140℃; for 72h;	91%

1-naphthol-2-sulfonic acid (567-18-0) + 1,1,2,2-tetrachloroethane (79-34-5) → 4-hydroxy-naphthalene-1,3-disulfonic acid (1857-16-5)

Conditions	Yield
	90%

methyl 5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-1,2-benzisothiazole-3-acetate + 1,1,2,2-tetrachloroethane (79-34-5) → methyl 5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-α-bromo-1,2-benzisothiazole-3-acetate

Conditions	Yield
With N-Bromosuccinimide; dibenzoyl peroxide	90%

trans-[Cl2(pyrazine)4ruthenium(II)] (449147-38-0) + silver trifluoromethanesulfonate (2923-28-6) + butan-1-ol (71-36-3) + 1,1,2,2-tetrachloroethane (79-34-5) → trans-[Cl2(pyrazine)4ruthenium(II)Ag]CF3SO3*(1,1,2,2-tetrachloroethane)*0.5(n-butanol)

Conditions	Yield
In 1,1,2,2-tetrachloroethylene; butan-1-ol a soln. of Ag salt (n-butanol) added dropwise to a soln. of Ru compd. (TCE), stored for 1 h; ppt. filtered, washed (n-butanol), dried (vac., 3 h); elem. anal.;	90%

C20N4H6(CH3)4(C2H5)2(C2H4COOC6H4NO2)2 + iron(II) acetate (1834-30-6, 2140-52-5, 3094-87-9) + 1,1,2,2-tetrachloroethane (79-34-5) → CH3COOFeC20N4H4(CH3)4(C2H5)2(C2H4COOC6H4NO2)2*CHCl2CHCl2

Conditions	Yield
With acetic anhydride In acetic acid stirring at 100°C for ca. 1 h in 1:1 mixture of AcOH and CHCl2CHCl2; evapn., dissolution in CHCl2CHCl2, filtration, evapn.; elem. anal.;	90%

1,1,2,2-tetrachloroethane (79-34-5) → 1,2,2-trichloroethyl fluosulfate (80337-48-0)

Conditions	Yield
With chlorine fluorosulfate 1.) -30 deg C, 1 h, 2.) 20 deg C, 2.5 h, 3.) 60 deg C, 1 h;	88.7%

water (7732-18-5) + Trimethylenediamine (109-76-2) + nickel(II) hydroxide + 1,1,2,2-tetrachloroethane (79-34-5) → (1,5,8,12-tetraaza-6,7,13,14-tetrachlorocyclotetradecane)diaquanickel(II) chloride

Conditions	Yield
In butan-1-ol byproducts: HCl; equimolar mixt. of Ni(OH)2, 1,1,2,2-tetrachloroethane and 1,3-diaminopropane in n-butanol stirred at room temp.; refluxed for ca. 8 h; stirred for ca. 12 min with water; filtered; aq. layer of filtrate sepd.; concd.; refrigerated; crystals washed with n-butanol and petroleum ether; elem. anal.;	88%

dichlorotetrakis(triphenylphosphine)ruthenium(II) (15555-77-8, 86470-43-1) + 2,3-S(C2H4S)2-1,4-Me2C10H4 (425615-15-2) + 1,1,2,2-tetrachloroethane (79-34-5) → (RuCl2(2,3-S(C2H4S)2-1,4-Me2C10H4-κS,S,S)(PPh3))*2(1,1,2,2-tetrachloroethane)

Conditions	Yield
In diethyl ether under Ar atm. mixt. ligand and (RuCl2(PPh3)4) in Et2O at room temp. for 5 min; ppt. was extd. with CH2Cl2, solvent was evapd, residue was crystd. from 1,1,2,2-tetrachloroethane-Et2O; elem. anal.;	88%

water (7732-18-5) + ethylenediamine (107-15-3) + nickel(II) hydroxide + 1,1,2,2-tetrachloroethane (79-34-5) → (1,4,7,10-tetraaza-5,6,11,12-tetrachlorocyclododecane)diaquanickel(II) chloride

Conditions	Yield
In butan-1-ol byproducts: HCl; Ni(OH)2 added to soln. of 1,1,2,2-tetrachloroethane and 1,2-diaminoethane (molar ratio 1:1:1) in n-butanol; stirred and refluxed for ca. 7 h; cooled; stirred for ca. 10 min with water; filtered; aq. layer of filtrate sepd.; concd.; refrigerated; crystals washed with n-butanol and petroleum ether; elem. anal.;	86%

1,2-dimethoxybenzene (91-16-7) + 4-chloro-benzoyl chloride (122-01-0) + 1,1,2,2-tetrachloroethane (79-34-5) → 4-chloro-3',4'-dimethoxy benzophenone (116412-83-0)

Conditions	Yield
With FeCl3; graphite	84.3%
With FeCl3; graphite	84.3%
graphite	81.3%

N-allyl-N-phenyl-2-methacrylamide (145784-90-3) + 1,1,2,2-tetrachloroethane (79-34-5) → cis-3,4-dimethyl-1-phenyl-3-(2,3,3-trichloroallyl)pyrrolidin-2-one + trans-3,4-dimethyl-1-phenyl-3-(2,3,3-trichloroallyl)pyrrolidin-2-one

Conditions	Yield
With tris(2,2'-bipyridyl)ruthenium dichloride; 4-methoxybenzenediazonium tetrafluoroborate; sodium carbonate In neat (no solvent) at 50℃; for 20h; Inert atmosphere; Schlenk technique; Irradiation;	A 83% B n/a

1,2-dimethoxybenzene (91-16-7) + 4-chlorotrichloromethylbenzene (5216-25-1) + 1,1,2,2-tetrachloroethane (79-34-5) → 4-chloro-3',4'-dimethoxy benzophenone (116412-83-0)

Conditions	Yield
graphite In water	79.5%

4-Methoxystyrene (637-69-4) + ethanol (64-17-5) + 1,1,2,2-tetrachloroethane (79-34-5) → 1-methoxy-4-(3,3,4,4-tetrachloro-1-ethoxybutyl)benzene

Conditions	Yield
With tetrakis(acetonitrile)copper(I)tetrafluoroborate; 4-methoxybenzenediazonium tetrafluoroborate; sodium carbonate at 80℃; for 6h; Schlenk technique; Inert atmosphere;	77%

1,1,2,2-tetrachloroethane (79-34-5) → Trichloroethylene (79-01-6)

Conditions	Yield
With hydrogenchloride; oxygen at 379.84℃; Reagent/catalyst; Temperature;	74.3%
With chlorine at 379.84℃; Gas phase; chemoselective reaction;	57.3%
at 350 - 400℃; bei der Einwirkung von Luft;

bis(N,N'-diphenyl-2,4-pentanediiminato)chromium(II) (238423-82-0) + 1,1,2,2-tetrachloroethane (79-34-5) → bis(N,N'-diphenyl-2,4-pentanediiminato)chlorochromium(III) (327028-24-0)

Conditions	Yield
In diethyl ether standard Schlenk techniques; tetrachloroethane added to soln. of Cr complex (molar ratio 1:2) in Et2O with stirring; stirred overnight; solvent evapd.; extd. with Et2O; evapd. slowly at room temp.; elem. anal.;	73%

propionaldehyde (123-38-6) + 1,1,2,2-tetrachloroethane (79-34-5) → 2,2-dichloropropanal (27313-32-2)

Conditions	Yield
In carbon dioxide; N,N-dimethyl-formamide	70%

1,1,2,2-tetrachloroethane (79-34-5) → 1,1,2,2-tetrachloroethylene (127-18-4) + Trichloroethylene (79-01-6)

Conditions	Yield
With hydrogenchloride; oxygen at 379.84℃; for 18h;	A 20.8% B 64.3%
With CuCl2/KCl/attapulgite; chlorine at 379.84℃; Gas phase; chemoselective reaction;	A 16.6% B 45%

1,1,2,2-tetrachloroethane (79-34-5) → 1,1,2,2-tetrachloroethylene (127-18-4) + Trichloroethylene (79-01-6) + pentachloroethane (76-01-7)

Conditions	Yield
With hydrogenchloride; oxygen at 379.84℃;	A 20.8% B 64.3% C 6.1%

[rhodium(chloro)(PhB(C6H4P(iPr)2))2]2 + [rhodium(chloro)(phenyl)(B(C6H4P(iPr)2))2] + [rhodium(chloro)(C6H4B(C6H4P(iPr)2))2] + 1,1,2,2-tetrachloroethane (79-34-5) → [rhodium(dichloro)(B(C6H4P(iPr)2))2]

Conditions	Yield
In 1,3,5-trimethyl-benzene at 170℃; for 18h; Inert atmosphere; Schlenk technique;	60%

oxalic acid (144-62-7) + 1,1,2,2-tetrachloroethane (79-34-5) → C6H2O8

Conditions	Yield
Stage #1: oxalic acid; 1,1,2,2-tetrachloroethane With sulfuric acid for 10h; Stage #2: With sulfur trioxide; mercury(II) sulfate at 60℃;	58.8%

methanol (67-56-1) + 5,10,15,20-tetra{[p-(1H-benzimidazol-1-yl)]phenyl}porphyrin zinc + water (7732-18-5) + mercury dichloride + 1,1,2,2-tetrachloroethane (79-34-5) → C72H44N12Zn*2HgCl2*2CH4O*2C2H2Cl4*4H2O

Conditions	Yield
	56%

Upstream product

• 156-59-2 cis-1,2-Dichloroethylene 
• 156-60-5 trans-1,2-dichloroethylene 
• 540-59-0 1,2-Dichloroethylene 
• 74-84-0 ethane 
• 67-66-3 chloroform 
• 16452-89-4 1,1,2-trichloro-2-iodo-ethane 
• 79-01-6 Trichloroethylene 
• 79-02-7 2,2-dichloroacetaldehyde 
• 107-06-2 1,2-dichloro-ethane 
• 60-29-7 diethyl ether 
• 67-72-1 hexachloroethane 
• 4294-57-9 para-methylphenylmagnesium bromide 
• 74-86-2 acetylene 
• 938-05-6 dibromamine-B 

Downstream Products

• 79-01-6 Trichloroethylene 
• 90005-54-2 2-amino-1-(3-hydroxyphenyl)ethyl ketone 
• 74-96-4 ethyl bromide 
• 352-93-2 diethyl sulphide 
• 14181-81-8 2-anilino-N,N'-diphenyl-acetamidine 
• 67-72-1 hexachloroethane 
• 100-56-1 phenylmercury(II) chloride 
• 71-43-2 benzene 
• 77753-21-0 1,1,1,4,4-pentachloro-but-2-ene 
• 13498-31-2 1,4-dichlorooctaphenyltetrasilane 
• 893-07-2 3-methyl-crotonaldehyde-(2,4-dinitro-phenylhydrazone) 
• 5153-28-6 diphenylbismuth(III) chloride 
• 632-50-8 1,1,2,2-tetraphenylethane 
• 92-52-4 biphenyl 

Relevant articles and documents

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Determination of the rate constant of the reaction of CCl2 with HCl

The rate constant of the reaction between CCl2 radicals and HCl was experimentally determined. The CCl2 radicals were obtained by infrared multiphoton dissociation of CDCl3. The time dependence of the CCl2 radic

ArF laser photolytic deposition and thermal modification of an ultrafine chlorohydrocarbon

MW ArF laser irradiation of gaseous cis-dichloroethene results in fast decomposition of this compound and in deposition of solid ultrafine Cl- and H-containing carbonaceous powder which is of interest due to its sub-microscopic structure and possible reactive modification of the C-Cl bonds. The product was characterized by electron microscopy, and FTIR and Raman spectra and it was revealed that HCl, H2, and C/H fragments are lost and graphitic features are adopted upon heating to 700°C.