α-trialaninecobalt(III)

Base Information

• Chemical Name: α-trialaninecobalt(III)
• CAS No.: 20616-36-8
• Molecular Formula: C₉H₁₈CoN₃O₆
• Molecular Weight: 323.252
• Mol file: 20616-36-8.mol

Synonyms:

Chemical Property of α-trialaninecobalt(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of α-trialaninecobalt(III)

There total 4 articles about α-trialaninecobalt(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

rac-Ala-OH (302-72-7,25191-17-7,18875-37-1) + cobalt(II) hydroxide → α-trialaninecobalt(III) (55448-50-5,170556-91-9,20467-67-8,28167-90-0,14653-39-5,20616-36-8,105499-90-9,15650-49-4,105617-21-8,105617-20-7,79466-43-6,18601-15-5,55328-27-3,21205-93-6,28167-89-7,31151-83-4)

Guidance literature:

With sulfur dioxide; In water; addn. of Co(OH)2 to DL-alanine in H2O; hot filtration after boiling for 5 h; concn. and storing of the filtrate; pptn. of violet DL-(Coal3); suspn. of the residue of the first filtration in H2O; treatment with SO2;; solving in 12 M H2SO4 soln., repptn. with H2O, washing + drying in air;;

DOI:10.1021/ja01109a004

Reference yield:

hexammine cobalt(III) chloride (10534-89-1) + rac-Ala-OH (302-72-7,25191-17-7,18875-37-1) → α-trialaninecobalt(III) (55448-50-5,170556-91-9,20467-67-8,28167-90-0,14653-39-5,20616-36-8,105499-90-9,15650-49-4,105617-21-8,105617-20-7,79466-43-6,18601-15-5,55328-27-3,21205-93-6,28167-89-7,31151-83-4)

Guidance literature:

In potassium hydroxide; mixing a mixt. of DL-alanine + (Coa6)Cl3 solns. with 3 n KOH soln. in small excess; heating; pptn. of red dl-(Coal3); evapn. of the mother liquor leads to violet DL-(Coal3);;

Reference yield:

cobalt(III)-aquoxide + rac-Ala-OH (302-72-7,25191-17-7,18875-37-1) → α-trialaninecobalt(III) (55448-50-5,170556-91-9,20467-67-8,28167-90-0,14653-39-5,20616-36-8,105499-90-9,15650-49-4,105617-21-8,105617-20-7,79466-43-6,18601-15-5,55328-27-3,21205-93-6,28167-89-7,31151-83-4)

Guidance literature:

In not given; small excess of cobalt aquoxide and DL-alanine; evaporation to dryness; addn. of hot H2O to the residue;;

upstream raw materials:

hexammine cobalt(III) chloride

rac-Ala-OH