Os(SnMe₃)H(CO)2(PPh₃)2

Base Information

Chemical Name:Os(SnMe₃)H(CO)2(PPh₃)2
CAS No.:678166-83-1
Molecular Formula:C₄₁H₄₀O₂OsP₂Sn
Molecular Weight:935.625
Hs Code.:

Os(SnMe<sub>3</sub>)H(CO)2(PPh<sub>3</sub>)2

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Os(SnMe₃)H(CO)2(PPh₃)2

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Technology Process of Os(SnMe₃)H(CO)2(PPh₃)2

There total 1 articles about Os(SnMe₃)H(CO)2(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 35880-55-8,64479-09-0
Os(CO)2(PPh₃)3

: 1631-73-8
trimethylstannane

: 678166-83-1,678166-84-2,677773-17-0,678166-85-3
Os(SnMe₃)H(CO)2(PPh₃)2

Guidance literature:: In benzene; Irradiation (UV/VIS); under N2; Me3SnH (0.592 mmol) was added to a yellow suspn. of Os-contg. compd. (0.494 mmol) in C6H6; the mixt. was irradiated with a 1000 W quartz-halogen lamp at room temp. for ca. 30 min; the vol. of the soln. was reduced (in vac.) to ca. 5 mL and ethanol was added; the solvent was removed in vac. from the ppt.; recrystn. from CH2Cl2-ethanol; elem. anal.;
DOI:10.1016/j.jorganchem.2003.11.021

Reference yield: 91.0%

: 678166-83-1,678166-84-2,677773-17-0,678166-85-3
Os(SnMe₃)H(CO)2(PPh₃)2

: 753-73-1
dimethyltin dichloride

: 678166-88-6,677773-18-1,678166-87-5,678166-86-4
Os(SnMe₂Cl)H(CO)2(PPh₃)2

Guidance literature:: In dichloromethane; a Schlenk tube was charged with Os-contg. compd. (0.213 mmol) and SnMe2Cl2 (0.213 mmol); CH2Cl2 was added; stirring at room temp. for ca. 16 h; all volatiles were removed in vac.; the solid was recrystd. from CH2Cl2/EtOH; the crystals were collected by vac. filtration, washed with EtOH and heptane and dried in vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2003.11.021

Reference yield: 90.0%

: 678166-83-1,678166-84-2,677773-17-0,678166-85-3
Os(SnMe₃)H(CO)2(PPh₃)2

: tin(IV) iodide

: 677773-19-2
Os(SnMeI₂)H(CO)2(PPh₃)2

Guidance literature:: In dichloromethane; Os-contg. compd. (0.376 mmol) and SnI4 (1.881 mmol) were dissolved in CH2Cl2; the suspn. was stirred at room temp. for ca. 16 h; all volatiles were removed in vac.; the solid was recrystd. from CH2Cl2-ethanol; elem. anal.;
DOI:10.1016/j.jorganchem.2003.11.021