CID 9815856

Base Information

• Chemical Name: CID 9815856
• CAS No.: 753-73-1
• Molecular Formula: C2H6Cl2Sn
• Molecular Weight: 219.686
• Hs Code.: 2931.00
• Mol file: 753-73-1.mol

Synonyms:AKOS032949805;D1338

Chemical Property of CID 9815856

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 15.7mmHg at 25°C
• Melting Point: 101-106 °C(lit.)
• Boiling Point: 124 °C at 760 mmHg
• Flash Point: 28.8 °C
• PSA: 0.00000
• Density: 1,397 g/cm3
• LogP: 2.16580
• Storage Temp.: 2-8°C
• Sensitive.: Moisture Sensitive
• Solubility.: methanol: 0.1 g/mL, clear
• Water Solubility.: Slightly soluble in water (20 g/L (20°C)). Solubility in other solvents (0.1 g/ml in methanol).
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 219.886858
• Heavy Atom Count: 5
• Complexity: 2.8

Purity/Quality:

99% ^*data from raw suppliers

DMT-C ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Sn+2]C.[Cl-].[Cl-]
• Uses: Used as a pharmaceutical intermediate. It is employed as a coating, plastic and rubber auxilliary agent. Used as methyl Tin stabilizer intermediates, catalysts for esterification reaction, raw material for glass coating.

Technology Process of CID 9815856

There total 125 articles about CID 9815856 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1,1-dimethyl-2,3,4,5-tetraphenylstannole (20195-60-2) → dimethyltin dichloride (753-73-1) + 1-chloro-2,3,4,5-tetraphenylborole (62707-11-3)

Guidance literature:

With boron trichloride; In dichloromethane; at -30 ℃; for 2h; Inert atmosphere;

DOI:10.1039/b808483a

Reference yield: 82.0%

boron trichloride (10294-34-5) + dimethylbis(pentafluorophenyl)tin (801-79-6) → bis(pentafluorophenyl)boron chloride (2720-03-8) + dimethyltin dichloride (753-73-1)

Guidance literature:

In n-heptane; at -70 - 105 ℃;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + dimethylbis(pentafluorophenyl)tin (801-79-6) → Pentafluorobenzene (363-72-4) + dimethyltin dichloride (753-73-1)

Guidance literature:

water-free HCl;;

upstream raw materials:

tetramethylstannane

boron trichloride

dimethylbis(pentafluorophenyl)tin

methylene chloride

Downstream raw materials:

diisopropyldimethyltin

di(t-butyl)dimethylstannane

dimethyl-dioctyl stannane

dimethylbis(pentafluorophenyl)tin

Refernces

• 1、 Loffredo, R. E.,Norman, A. D.. "". . p. 5587 - 5588. Retrieved 1971.
• 2、 Herberich,Hessner. "". . p. C36,C38,C39,C40. Retrieved 1978.
• 3、 -. "TIN COMPOUND, METHOD OF SYNTHESIZING THE SAME, TIN PRECURSOR COMPOUND FOR ATOMIC LAYER DEPOSITION, AND METHOD OF FORMING TIN-CONTAINING MATERIAL FILM". Paragraph 0133-0139. . Retrieved 2018/06/15.
• 4、 Duffy, Ian R.,Leigh, William J.. "Direct Detection, Dimerization, and Chemical Trapping of Dimethyl- and Diphenylstannylene from Photolysis of Stannacyclopent-3-enes in Solution". supporting information. p. 5029 - 5044. Retrieved 2015/11/09.