Technology Process of syn-(PhP(C5H4)2)2Fe2
There total 8 articles about syn-(PhP(C5H4)2)2Fe2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
CF3SO3CH3; P(N(CH3)2)3;
In
dichloromethane;
under N2, Schlenk techniques; addn. of CF3SO3Me to soln. of anti-(Fe(C5H4)2P(S)Ph)2 in CH2Cl2, stirring at room temp. for 3 h, evapd. under vac., residue dissolved in CH2Cl2, addn. of P(NMe2)3 at room temp., stirringfor 3 h; evapd. under vac., residue washed with CH2Cl2/ether and pure ether, dried under vac.;, elem. anal.;
DOI:10.1021/om049155w
- Guidance literature:
-
With
Si2Cl6;
In
benzene;
under N2, Schlenk techniques; addn. of excess amt. of Si2Cl6 to soln. ofsyn-(Fe(C5H4)2P(S)Ph)2 in benzene, mixt. refluxed for 1 d; cooling to room temp., addn. of 30% aq. NaOH, org. layer sepd. and washed with water, dried over MgSO4, filtration, filtrate evapd. under vac., recrystn. from CH2Cl2/hexane, washed with hexane and ether, dried under vac.; elem. anal.;
DOI:10.1021/om049155w
- Guidance literature:
-
With
Si2Cl6;
In
benzene;
under N2, Schlenk techniques; addn. of excess amt. of Si2Cl6 to soln. ofanti-(Fe(C5H4)2P(S)Ph)2 in benzene, mixt. refluxed for 1 d; cooling to room temp., addn. of 30% aq. NaOH, org. layer sepd. and washed with water, dried over MgSO4, filtration, filtrate evapd. under vac., recrystn. from CH2Cl2/hexane, washed with hexane and ether, dried under vac.;
DOI:10.1021/om049155w
![[(Fe((C<sub>5</sub>H<sub>4</sub>)2P(S)C<sub>6</sub>H<sub>5</sub>))2]](/Databaselist/images/loading.webp)
