zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin

Base Information

• Chemical Name: zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin
• CAS No.: 934630-84-9
• Molecular Formula: C₄₈H₃₂N₄Zn
• Molecular Weight: 730.199
• Mol file: 934630-84-9.mol

Synonyms:

Chemical Property of zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin

There total 1 articles about zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin trihydrate + zinc diacetate (557-34-6) → zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin (934630-84-9)

Guidance literature:

In methanol; dichloromethane; Zn salt in MeOH added to a soln. of ligand in CH2Cl2, stirred at room temp. for 1 d; filtered, solvent-removed, chromd. (alumina, CH2Cl2), solvent-removed, recrystd. (CH2Cl2/MeOH); elem. anal.;

DOI:10.1021/ic062303l

Reference yield: 35.0%

zinc(II) 2,3-(β-methylpropeno)-5,10,15,20-tetraphenylporphyrin (934630-84-9) + iron(II) chloride → iron(II) bis[1,2-[zinc(II)-5,10,15,20-tetraphenylporphyrinato]-3-methyl-cyclopentadienide]

Guidance literature:

With lithium diisopropylamide; In tetrahydrofuran; lithium diisopropylamide in THF added at 0°C to a soln. Zn complex, stirred at 0°C, allowed to warm to room temp., FeCl2 added under air-free conditions, refluxed under Ar; cooled, filtered, evapd. (vac.), dissolved in CH2Cl2, washed (HCl soln.,H2O), solvent-removed, purified using Sephadex LH-20 (THF);

DOI:10.1021/ic062303l

upstream raw materials:

zinc diacetate