[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%

Base Information

• Chemical Name: [mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%
• CAS No.: 37095-27-5
• Molecular Formula: C25H22P2.2AuCl
• Molecular Weight: 849.236
• Mol file: 37095-27-5.mol

Synonyms:[mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%;[μ-Bis(diphenylphosphino) methane]dichlorodigold(I), 99%;[Mu-Bis(diphenylphosphino)Methane]dichlorodigold(III);[mu-Bis(diphenylphosphino)methane]dichlorodigold(I), 99%;[Mu-Bis(diphenylphosphino)Methane]dichlorodigold(I),99%;[μ-Bis(diphenylphosphino)Methane]dichlorodigold(I),98% (DPPM)(AuCl)2;(mu-Bis(diphenylphosphino)methane)bis(chlorogold);[mu-Bis(diphenylphosphino)methane]dichlorodigold

Chemical Property of [mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%

Chemical Property:

• Melting Point: 271-272℃
• PSA: 27.18000
• LogP: -0.78730

Purity/Quality:

98%Min ^*data from raw suppliers

[μ-Bis(diphenylphosphino)methane]dichlorodigold(I), 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Used for Pharmacological studies involving the anticancer activity of gold(I)-phosphine complexes as autophagy-inducing agentsTriplet luminescent light emitting diodes with low turn-on voltageCatalyst for:Stereoselective preparation of vinyltetrahydrofuran via intramolecular hydroalkoxylationHydroamination and hydroalkoxylation reactionsAsymmetric transition metal catalysisGold(I) catalyzed intramolecular Schmidt reactions of homopropargyl azides

Technology Process of [mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99%

There total 12 articles about [mu-Bis(diphenylphosphino)methane]dichlorodigold(III),99% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

chloro(dimethylsulfide) gold(I) (29892-37-3) + bis-diphenylphosphinomethane (2071-20-7) → (bis(diphenylphosphino)methane)bis(chlorogold(I)) (37095-27-5)

Guidance literature:

In acetone; addn. of soln. of dppm (1 equiv.) in acetone to suspn. of (AuCl(SMe)2) (2 equiv.) in acetone; stirring for 2 h; pptn., filtration, washing with acetone, diethyl ether and pentane, drying under vac.;

DOI:10.1039/b005251p

Reference yield: 88.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + bis-diphenylphosphinomethane (2071-20-7) → (bis(diphenylphosphino)methane)bis(chlorogold(I)) (37095-27-5)

Guidance literature:

In ethanol; at 20 ℃; for 0.5h;

DOI:10.1021/jacs.7b06668

Reference yield: 53.0%

bis(triphenylphosphine)nitrogen gold dichloride (106402-58-8) + [Au2(μ-(PPh2)2CH2)2](ClO4)2 → (bis(diphenylphosphino)methane)bis(chlorogold(I)) (37095-27-5)

Guidance literature:

In dichloromethane; byproducts: [N(PPh3)2]ClO4; molar ratio Au2-dppm complex:AuCl2(1-) complex=1:2, stirring (room temp., 3 h); concn., pptn. on Et2O addn., washing (MeOH/Et2O=1:1);

DOI:10.1039/DT9950001255

upstream raw materials:

(tetrahydrothiophene)gold(I) chloride

bis-diphenylphosphinomethane

diethyl sulfide gold chloride

{PdCl(μ-dppm)}2

Downstream raw materials:

(AuCl)2(μ-cis-1,2-bis(diphenylphosphino)ethylene)

Pt₂Cl(ONO₂)((C₆H₅)2PCH₂P(C₆H₅)2)2

Refernces

• 1、 Harper, Matthew J.,Emmett, Edward J.,Bower, John F.,Russell, Christopher A.. "Oxidative 1,2-Difunctionalization of Ethylene via Gold-Catalyzed Oxyarylation". supporting information. p. 12386 - 12389. Retrieved 2017/09/22.
• 2、 Molter, Anja,Mohr, Fabian,Rust, Joerg,Lehmann, Christian W.. "Synthesis and structural studies of some gold(I) complexes containing selenoureato ligands". . p. 10586 - 10591,6. Retrieved 2012/12/12.