titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride

Base Information

Chemical Name:titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride
CAS No.:940964-72-7
Molecular Formula:C₃₁H₂₃Cl₂NO₂Ti
Molecular Weight:560.315
Hs Code.:

titanium<sup>(4+)</sup> tetraphenyl-2,6-pyridinedimethoxide dichloride

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Chemical Property of titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride

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Technology Process of titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride

There total 3 articles about titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 7550-45-0
titanium tetrachloride

: 58451-82-4
2,6-bis-(1-hydroxy-1,1-diphenyl-methyl) pyridine

: 940964-72-7
titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride

Guidance literature:: With butyllithium; In hexane; toluene; under Ar atm.; to stirred soln. of ligand in toluene under Ar atm. was added soln. of BuLi in hexane at -78°C; mixt. was slowly brought to room temp.; stirred for 4 h; cooled to -78°C; metal salt (1 equiv.) added; mixt. stirred for 12 h; filtered; org. layer evapd.; recrystd. (toluene); elem. anal.;
DOI:10.1134/S0036023611040255

Reference yield: 20.0%

: 16753-20-1
bis(dimethylamido)titanium(IV) dichloride

: 58451-82-4
2,6-bis-(1-hydroxy-1,1-diphenyl-methyl) pyridine

: 940964-72-7
titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride

Guidance literature:: In chloroform; under Ar, Schlenk techniques; soln. of ligand added to suspn. of Ti compd. (1:1) at 20°C, stirred for 60 h; filtered (celite), evapd., crystd. (CH2Cl2), elem. anal.;
DOI:10.1016/j.ica.2006.10.027

Reference yield:

: titanium(IV) chloride tetrahydrofuran

: 58451-82-4
2,6-bis-(1-hydroxy-1,1-diphenyl-methyl) pyridine

: [Ti(2,5-bis(hydroxy(diphenyl)methyl)pyridine(-2H))2]

: 940964-72-7
titanium⁽⁴⁺⁾ tetraphenyl-2,6-pyridinedimethoxide dichloride

Guidance literature:: With Et₃N; In dichloromethane; under Ar, Schlenk techniques; soln. of ligand and Et3N added to soln. ofof Ti compd. (1:2:1) at -30°C, stirred for 1 h, warmed to room t emp., stirred overnight; evapd., extd. (benzene), filtered (celite), crystd. (CH2Cl2/heptane);
DOI:10.1016/j.ica.2006.10.027