[cobalt(III)(N,N-dimethyldithiocarbamate)3]

Base Information

Chemical Name:[cobalt(III)(N,N-dimethyldithiocarbamate)3]
CAS No.:23677-76-1
Molecular Formula:C₉H₁₈CoN₃S₆
Molecular Weight:419.651
Hs Code.:

Synonyms:

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Chemical Property of [cobalt(III)(N,N-dimethyldithiocarbamate)3]

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Technology Process of [cobalt(III)(N,N-dimethyldithiocarbamate)3]

There total 8 articles about [cobalt(III)(N,N-dimethyldithiocarbamate)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.9%

: 15684-35-2
cobalt(II) tetrafluoroborate hexahydrate

: 137-26-8,93196-73-7
Thiram

: 1486-28-8
diphenyl(methyl)phosphine

: 69176-60-9,69176-59-6,23677-76-1
[cobalt(III)(N,N-dimethyldithiocarbamate)3]

: 403824-34-0,404570-73-6
trans-[Co(N,N-dimethyldithiocarbamato)2(PMePh₂)2]BF₄

: cis-[Co(N,N-dimethyldithiocarbamato)2(PMePh₂)2]BF₄

Guidance literature:: In ethanol; dichloromethane; to MeOH soln. of Co-contg. compd. (2.87 mmol) PMePh2 (5.74 mmol) was added with stirring; then a soln. of S-contg. compd. (2.87 mmol) in a mixt.of CH2Cl2 and MeOH was added with stirring for 2 h at room temp.; under Ar; the react. mixt. was filtered; the filtrate was concd. to dryness under reduced pressure; the residue was washed with diethyl ether; the compds.were dissolved in hot MeOH; cooling in a refrigerator overnight; recrys tn. from CH2Cl2/MeOH; elem. anal.;
DOI:10.1246/bcsj.74.2349

Reference yield: 45.0%

: 15684-35-2
cobalt(II) tetrafluoroborate hexahydrate

: 137-26-8,93196-73-7
Thiram

: 603-35-0
triphenylphosphine

: 69176-60-9,69176-59-6,23677-76-1
[cobalt(III)(N,N-dimethyldithiocarbamate)3]

: trans-{Co(dtc)2(PPh₃)2}BF₄

Guidance literature:: In ethanol; dichloromethane; to EtOH soln. of Co-contg. compd. (5.90 mmol) and PPh3 (11.8 mmol) was added a soln. of S-contg. compd. (5.86 mmol) in a mixt. of CH2Cl2 and EtOH with stirring for 1 h at room temp.; under Ar; the ppt. was collected by filtration; re-pptn. by addn. of diethyl ether; the ppt. was filtered off, and dissolved in a mixt. of CH2Cl2 and EtOH; slow evapn. of the solvent; elem. anal.;
DOI:10.1246/bcsj.74.2349

Reference yield: 25.0%

: ammonium hexafluorophosphate

: 15684-35-2
cobalt(II) tetrafluoroborate hexahydrate

: 4020-99-9
diphenylphosphinous acid methyl ester

: 137-26-8,93196-73-7
Thiram

: 69176-60-9,69176-59-6,23677-76-1
[cobalt(III)(N,N-dimethyldithiocarbamate)3]

: cis-[Co(N,N-dimethyldithiocarbamate)2(P(OMe)Ph₂)2]PF₆

Guidance literature:: In tetrahydrofuran; methanol; dichloromethane; to ice-cold MeOH soln. Co(BF4)2*6H2O containing phosphine ise-cold soln.tetramethylthiuramdisulfide in CH2Cl2-THF was added dropwise and stirre d for 2 h, soln. was evapd. to dryness in vacuo, residue was extd. with MeOH, NH4PF6 was added; soln. was concd., ppt. was washed with Et2O and air-dried; elem. anal.;
DOI:10.1039/b301712e