{(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride}

Base Information

• Chemical Name: {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride}
• CAS No.: 156398-89-9
• Molecular Formula: C₃₆H₄₀Cl₂N₂Zn
• Molecular Weight: 637.023
• Mol file: 156398-89-9.mol

Synonyms:

Chemical Property of {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride}

There total 3 articles about {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

zinc(II) chloride (7646-85-7,24359-56-6) + 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene (153625-67-3) → {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride} (156398-89-9)

Guidance literature:

In acetic acid; N-compd. was added in one portion to ZnCl2 in glacial acetic acid; solid was filtered off, washed 3 times with Et2O, dried in air, recrystd. from hexane/CH2Cl2, elem. anal.;

DOI:10.1016/j.poly.2004.06.023

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + acenaphthene quinone (82-86-0) → {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride} (156398-89-9)

Guidance literature:

Multi-step reaction with 2 steps

1: acid / methanol

2: methanol

With acid; In methanol;

DOI:10.2533/chimia.2017.773

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) + zinc(II) chloride (7646-85-7,24359-56-6) + acenaphthene quinone (82-86-0) → {(bis(2,6-diisopropylphenylimino)acenaphthene)zinc chloride} (156398-89-9)

Guidance literature:

In acetic acid; the mixture of the starting compds. in glacial acetic acid is stirred at reflux for 30 min, cooled to 20°C; the solid is filtd. off, washed (acetic acid, diethyl ether), air dried, yield 70-99 %;

DOI:10.1002/recl.19941130204

upstream raw materials:

2,6-diisopropylbenzenamine

zinc(II) chloride

acenaphthene quinone

1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene