Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,6-bis(1-methylethyl)-

Base Information

• Chemical Name: Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,6-bis(1-methylethyl)-
• CAS No.: 153625-67-3
• Molecular Formula: C36H40N2
• Molecular Weight: 500.727
• Mol file: 153625-67-3.mol

Synonyms:dipp-BIAN;N,N'-bis(2,6-diisopropyl)phenylacenaphthenequinonediimine;N,N'-bis(2,6-diisopropylphenyl)acenaphthenequinonediimine;dpp-bian;1,2-bis(o,o'-bis(isopropyl)phenylimino)acenaphthene;DippBIAN;

Chemical Property of Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,6-bis(1-methylethyl)-

Chemical Property:

• PSA: 24.72000
• LogP: 10.58860

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,6-bis(1-methylethyl)-

There total 9 articles about Benzenamine, N,N'-1,2-acenaphthylenediylidenebis[2,6-bis(1-methylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

2,6-diisopropylbenzenamine (24544-04-5) + acenaphthene quinone (82-86-0) → 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene (153625-67-3)

Guidance literature:

acenaphthene quinone; With acetic acid; In acetonitrile; at 80 ℃; Inert atmosphere;

2,6-diisopropylbenzenamine; for 5.5h; Reflux; Inert atmosphere;

DOI:10.1021/om1000327

Reference yield: 91.0%

(2E)-2-[(2,6-diisopropylphenyl)imino]acenaphthylen-1(2H)-one (187605-59-0) + 2,6-diisopropylbenzenamine (24544-04-5) → 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene (153625-67-3)

Guidance literature:

Inert atmosphere; Schlenk technique;

DOI:10.1002/aoc.4355

Reference yield: 80.0%

2,6-diisopropylbenzenamine (24544-04-5) + acenaphthene quinone (82-86-0) → (2E)-2-[(2,6-diisopropylphenyl)imino]acenaphthylen-1(2H)-one (913618-66-3) + 1,2-bis-[(2,6-diisopropylphenyl)imino]acenaphthene (153625-67-3)

Guidance literature:

With sodium sulfate; In methanol; at 45 ℃; for 10h;

DOI:10.1002/zaac.201200189

upstream raw materials:

2,6-diisopropylbenzenamine

acenaphthene quinone

(2E)-2-[(2,6-diisopropylphenyl)imino]acenaphthylen-1(2H)-one

aniline

Downstream raw materials:

{bis((2,6-diisopropylphenyl)imino)acenaphthene}(maleic anhydride)palladium⁽⁰⁾

PdCl₂(bis(o,o'-iPr₂C₆H₃-imino)acenaphthene)

ruthenium pentacarbonyl

Ru(CO)3(bis(2,6-iPr₂C₆H₃-imino)acenaphthene)