azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate

Base Information

• Chemical Name: azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate
• CAS No.: 716337-27-8
• Molecular Formula: C₄₄H₄₃FeN₃P₂Rh*F₆P
• Molecular Weight: 979.51
• Mol file: 716337-27-8.mol

Synonyms:

Chemical Property of azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate

There total 1 articles about azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.6%

chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate (223242-63-5) + trimethylsilylazide (4648-54-8) + silver nitrate → azido-2κN-bis[μ-(1η5:2κP)-diphenylphosphinocyclopentadienyl][2(η5)-pentamethylcyclopentadienyl]iron(III)rhodium(III) hexafluorophosphate (716337-27-8)

Guidance literature:

In dichloromethane; acetone; soln. of ((RhC5(CH3)5Cl)(Fe(C5H4P(C6H5)2)2)) and AgNO3 in CH2Cl2/acetonestirred for 3 h at room temp.; evapd. under vac.; solid extracted with CH2Cl2; neat N3Si(CH3)3 added (molar ratio 1:3:1); soln. stirred for 18 h; solvent removed; residue washed with diethyl ether; recrystd. from CH2Cl2/hexane; elem. anal.;

DOI:10.1107/S0108270104004779

upstream raw materials:

chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

trimethylsilylazide