chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

Base Information

Chemical Name:chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate
CAS No.:223242-63-5
Molecular Formula:C₄₄H₄₃ClFeP₂Rh*F₆P
Molecular Weight:972.943
Hs Code.:

Synonyms:

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Chemical Property of chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

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Technology Process of chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

There total 2 articles about chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: sodium hexaflorophosphate

: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

: 223242-63-5
chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

Guidance literature:: In dichloromethane; acetone; N2-atmosphere; addn. of excess of NaPF6 to mixt. of 1 equiv. of Rh-complex and 2 equiv. of Fe-complex (in CH2Cl2/Me2CO=1:1), stirring (room temp., 3 h); solvent removal (reduced pressure), extn. into CH2Cl2, concn., crystn. on Et2O addn.; elem. anal.;
DOI:10.1016/S0022-328X(98)00939-5

Reference yield:

: 12150-46-8
1,1'-bis-(diphenylphosphino)ferrocene

: sodium hexaflorophosphate

: [(η(5)-pentamethylcyclopentadienyl)RhCl2]2(μ-1,1'-bis(diphenylphosphino)ferrocene)2

: 223242-63-5
chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

Guidance literature:: In not given;
DOI:10.1016/S0022-328X(98)00939-5

Reference yield: 77.0%

: sodium hexaflorophosphate

: 223242-63-5
chloro(1,1'-bis(diphenylphosphino)ferrocene)(pentamethylcyclopentadienyl)rhodium(III) hexafluorophosphate

: 75-05-8,26809-02-9
acetonitrile

: [(η(5)-pentamethylcyclopentadienyl)Rh(MeCN)(μ-1,1'-bis(diphenylphosphino)ferrocene-P,P')](PF6)2

Guidance literature:: With AgNO₃; In acetonitrile; N2-atmosphere; addn. of excess of NaPF6 to equimolar amts. of RhFe-complex and AgNO3, stirring for 3 h; solvent removal (reduced pressure), extn. into CH2Cl2, concn., crystn. on Et2O addn.; elem. anal.;
DOI:10.1016/S0022-328X(98)00939-5