triphenyl(4H-cyclopenta[b]thiophen-4-yl)stannane

Base Information

• Chemical Name: triphenyl(4H-cyclopenta[b]thiophen-4-yl)stannane
• CAS No.: 312637-05-1
• Molecular Formula: C₂₈H₂₆SSn
• Molecular Weight: 513.29
• Mol file: 312637-05-1.mol

Synonyms:

Chemical Property of triphenyl(4H-cyclopenta[b]thiophen-4-yl)stannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of triphenyl(4H-cyclopenta[b]thiophen-4-yl)stannane

There total 1 articles about triphenyl(4H-cyclopenta[b]thiophen-4-yl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

CH3C5H3CHC(C2H5)S (312637-09-5) + CH3C5H3CHC(C2H5)S (312637-08-4) + triphenyltin chloride (639-58-7) → triphenyl(4H-cyclopenta[b]thiophen-4-yl)stannane (312637-05-1)

Guidance literature:

With BuLi; In diethyl ether; hexane; BuLi in hexane was added to stirred soln. of thiophene deriv. in Et2O at ca. 20°, stirred for 2 h, cooled to -78°; Ph3SnCl added;mixt. warmed to ca. 20°, stirred for 1 h; concd., hexane added; cooled to -78° for 18 h; crystals sepd.; identified by elem. anal., NMR, mass spectra and single crystal X-ray diffraction;

DOI:10.1007/BF02495775

upstream raw materials:

CH₃C₅H₃CHC(C₂H₅)S

CH₃C₅H₃CHC(C₂H₅)S

triphenyltin chloride