Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer

Base Information

Chemical Name:Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer
CAS No.:1051971-74-4
Molecular Formula:C96H92Br2N8O16Zn2
Molecular Weight:1904.42
Hs Code.:

Synonyms:2,7-Dibromo-9,9'-spiro-bifluorene

Suppliers and Price of Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 12 raw suppliers

Chemical Property of Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer

Chemical Property:

Appearance/Colour:solid
Melting Point:>250 °C(Solv: dichloromethane (75-09-2); pentane (109-66-0))
PSA：179.44000
LogP:8.63620

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer

There total 2 articles about Dibromo zinc bis[3-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]phenyl]porphyrin-ethinyl dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1062503-88-1
C₄₈H₄₇BrN₄O₈Zn

: 1051971-74-4
C₉₆H₉₂Br₂N₈O₁₆Zn₂

Guidance literature:: C₄₈H₄₇BrN₄O₈Zn; With oxygen; In dichloromethane; for 0.25h;

With copper(l) chloride; In dichloromethane; for 0.0333333h;

With N,N,N,N,-tetramethylethylenediamine; for 0.333333h;

Reference yield: 77.0%

: 1062503-88-1
Zn((MeO(CH₂CH₂O)3C₆H₄)2(HCC)(Br)C₂₀H₈N₂)

: 1051971-74-4
Zn₂((MeO(CH₂CH₂O)3C₆H₄)2(Br)C₂₀H₈N₂C₄C₂₀H₈N₄(Br)(C₆H₄(OCH₂CH₂)3OMe)2)

Guidance literature:: With air; copper(l) chloride; In dichloromethane; stirring CH2Cl2 soln. of porphyrin deriv. in air for 15 min, addn. of CuCl, stirring for 2 min, addn. of amine deriv., stirring for 20 min; addn. of water, washing with water, chromy. (silica, CH2Cl2/methanol (98:2)), size exclusion chromy. (Bio Beads S-X1, THF), chromy. (silica, CH2Cl2/methanol (98.7:1.3)), recrystn. (CH2Cl2/pentane), NMR and MALDI;
DOI:10.1039/b814789b

Reference yield: 78.0%

: 2510-22-7
4-pyridylacetylene

: 1051971-74-4
C₉₆H₉₂Br₂N₈O₁₆Zn₂

: 1051971-75-5
C₁₁₀H₁₀₀N₁₀O₁₆Zn₂

Guidance literature:: With triethylamine; triphenylphosphine; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; copper(l) iodide; In N,N-dimethyl-formamide; at 40 ℃; for 3h;