(2R,3RS)-2--1-penten-3-ol

Base Information

Chemical Name:(2R,3RS)-2--1-penten-3-ol
CAS No.:122213-72-3
Molecular Formula:C₂₄H₂₃NO
Molecular Weight:341.453
Hs Code.:

(2R,3RS)-2-<N-(9-phenylfluoren-9-yl)amino>-1-penten-3-ol

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3RS)-2--1-penten-3-ol

Chemical Property:

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Technology Process of (2R,3RS)-2--1-penten-3-ol

There total 8 articles about (2R,3RS)-2--1-penten-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 917-54-4
methyllithium

: 122213-71-2
N-(9-phenylfluoren-9-yl)-D-vinylglicinal

: 122213-72-3,122213-82-5
(2R,3RS)-2--1-penten-3-ol

Guidance literature:: In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.333333h;
DOI:10.1021/jo00277a016

Reference yield:

: 122213-51-8
N-(9-phenylfluoren-9-yl)-L-serine isoxazolidide

: 122213-72-3,122213-82-5
(2R,3RS)-2--1-penten-3-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 99 percent / Et₃N / toluene / 0.25 h / 0 °C

2: 62 percent / LiAlH₄ / tetrahydrofuran / 0.25 h / -78 °C

3: 77 percent / tetrahydrofuran / 1.) -40 deg C, 10 min, 2.) 30 deg C, 10 min

4: 81 percent / 1 M KOH / ethanol / 24 h / Heating

5: 40 percent / 1.) dimethyl sulfide, N-chlorosuccinimide, 2.) Et₃N / toluene / 5 h / -25 °C

6: 47 percent / tetrahydrofuran; diethyl ether / 0.33 h / -78 °C

With potassium hydroxide; N-chloro-succinimide; lithium aluminium tetrahydride; dimethylsulfide; triethylamine; In tetrahydrofuran; diethyl ether; ethanol; toluene;
DOI:10.1021/jo00277a016

Reference yield:

: 122213-53-0
(4S)-2-oxo-3-(9-phenylfluoren-9-yl)oxazolidine-4-carboxylic acid isoxazolidide

: 122213-72-3,122213-82-5
(2R,3RS)-2--1-penten-3-ol

Guidance literature:: Multi-step reaction with 5 steps

1: 62 percent / LiAlH₄ / tetrahydrofuran / 0.25 h / -78 °C

2: 77 percent / tetrahydrofuran / 1.) -40 deg C, 10 min, 2.) 30 deg C, 10 min

3: 81 percent / 1 M KOH / ethanol / 24 h / Heating

4: 40 percent / 1.) dimethyl sulfide, N-chlorosuccinimide, 2.) Et₃N / toluene / 5 h / -25 °C

5: 47 percent / tetrahydrofuran; diethyl ether / 0.33 h / -78 °C

With potassium hydroxide; N-chloro-succinimide; lithium aluminium tetrahydride; dimethylsulfide; triethylamine; In tetrahydrofuran; diethyl ether; ethanol; toluene;
DOI:10.1021/jo00277a016