dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

Base Information

Chemical Name:dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride
CAS No.:85233-84-7
Molecular Formula:C₄₂H₄₂Cl₂NP₃Rh*Cl
Molecular Weight:862.988
Hs Code.:

Synonyms:

Suppliers and Price of dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

There total 2 articles about dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: rhodium trichloride hydrate

: 15114-55-3
tris(2-(diphenylphosphino)ethyl)amine

: 85233-84-7
dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

Guidance literature:: In methanol; refluxing (4-5 h); concn. to a small volume, addn. of Et2O; ppt. filtered, washed with Et2O, recrystd. from CH2Cl2/n-hexane; elem. anal.;

Reference yield: 60.0%

: rhodium(III) trichloride hydrate

: 15114-55-3
tris(2-(diphenylphosphino)ethyl)amine

: 85233-84-7
dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

Guidance literature:: In ethanol; under N2, solid ligand added to RhCl3*aq soln. in EtOH, refluxed for 4 h, cooled; filtered, concd., crystals filtered off, dried in vac., recrystd. from CH2Cl2 and EtOH; elem. anal.;
DOI:10.1016/S0020-1693(00)83549-5

Reference yield: 75.0%

: potassium cyanide

: 85233-84-7
dichlorotris(2-(diphenylphosphino)ethyl)aminerhodium(III) chloride

: 118681-70-2
{(NP₃)Rh(CN)2}BPh₄

Guidance literature:: In methanol; acetone; soln. of complex with methanolic soln. of KCN stirred (12 h, N2), n-hexane added; ppt. filtered, washed with methanol, water, ethanol and light ether, recrystd. from THF/methanol mixt. in presence of NaBPh4;