[Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2]

Base Information

• Chemical Name: [Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2]
• CAS No.: 340698-82-0
• Molecular Formula: C₄₂H₃₆O₂P₂PtS₂
• Molecular Weight: 893.906
• Mol file: 340698-82-0.mol

Synonyms:

Chemical Property of [Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2]

There total 1 articles about [Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + dithallium 2,2-diacetyl-1,1-ethylenedithiolate + triphenylphosphine (603-35-0) → thallium chloride (55172-29-7,7791-12-0) + [Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2] (340698-82-0)

Guidance literature:

In dichloromethane; to a suspn. of Tl-contg. compd. (0.41 mmol) in CH2Cl2 were added an equimolar amt. of Pt-contg. compd. and 2 equiv. of PPh3; stirring for 24 h; the suspn. was filtered, the soln. concd. under vac. and Et2O was added to ppt. yellow solid; the solid was filtered, washed with Et2O, and suction dried; elem. anal.;

DOI:10.1021/ic000996e

Reference yield: 99.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + [Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2] (340698-82-0) + silver perchlorate → [(Pt(PPh3)2)(Au(PPh3))2(S2C=C(C(O)Me)2)](ClO4)2 + silver(I) chloride

Guidance literature:

In acetone; under N2 atm. 2 equiv. (AuCl(PPh3)) and AgClO4 were reacted in acetone for 0.5 h, AgCl was filtered off, soln. was added dropwise to soln. Pt complex in acetone and stirred for 3 h; react. mixt. was filtered and concd. under vac., Et2O was added, solid was recrystd. from acetone and Et2O, and dried by suction and at 60°C in oven; elem. anal.;

DOI:10.1021/ic010488k

Reference yield: 92.0%

[Pt(η2-2,2-diacetyl-1,1-ethylenedithiolato)(PPh3)2] (340698-82-0) + silver perchlorate + triphenylphosphine (603-35-0) → [(Pt(PPh3)2)(Ag(PPh3)2)(μ2,η2-(S,S')-(S2CC(C(O)Me)2))]

Guidance literature:

In acetone; to a soln. of Pt-contg. compd. (0.09 mmol) in acetone an equimolar amt. of AgClO4 and 2 equiv. of PPh3 were added; the soln. was stirred for 4 hin the dark; the soln. was concd. and Et2O was added to ppt. the solid; it was filtered, washed with Et2O, and suction-dried; elem. anal.;

DOI:10.1021/ic000996e

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

triphenylphosphine