phenylmercurytrifluoromethanesulfonate

Base Information

Chemical Name:phenylmercurytrifluoromethanesulfonate
CAS No.:75726-02-2
Molecular Formula:C₇H₅F₃HgO₃S
Molecular Weight:426.766
Hs Code.:

Synonyms:

Suppliers and Price of phenylmercurytrifluoromethanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of phenylmercurytrifluoromethanesulfonate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of phenylmercurytrifluoromethanesulfonate

There total 2 articles about phenylmercurytrifluoromethanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: hexakis(dimethyl sulfoxide)mercury(II) trifluoromethanesulfonate

: 587-85-9,1337-09-3
diphenylmercury(II)

: {(C₆H₅)2Hg₃}⁽²⁺⁾*2O₃SCF₃^(1-)={(C₆H₅)2Hg₃}(O₃SCF₃)2

: 75726-02-2
{C₆H₅Hg}⁽¹⁺⁾*O₃SCF₃^(1-)={C₆H₅Hg}O₃SCF₃

Guidance literature:: In dichloromethane; Electrolysis; controlled potential oxidative electrolysis at a Hg pool electrode in CH2Cl2 at 20°C in the presence of 0.1 M Bu4NClO4; not isolated;
DOI:10.1016/S0020-1693(00)80821-X

Reference yield:

: 603-33-8
triphenylbismuthane

: {(C₆H₅)2Hg₃}⁽²⁺⁾*2O₃SCF₃^(1-)={(C₆H₅)2Hg₃}(O₃SCF₃)2

: 75726-02-2
{C₆H₅Hg}⁽¹⁺⁾*O₃SCF₃^(1-)={C₆H₅Hg}O₃SCF₃

Guidance literature:: Multi-step reaction with 2 steps

1: dichloromethane

2: dichloromethane

In dichloromethane;
DOI:10.1016/S0020-1693(00)80821-X

Reference yield: 75.0%

: [Ir(=C((t)Bu)P(Cy))(CO)(PPh₃)2]

: 75726-02-2
phenylmercurytrifluoromethanesulfonate

: [Ir(=C((t)Bu)P[Hg(Ph)](Cy))(CO)(PPh₃)2][SO₃CF₃]

Guidance literature:: In tetrahydrofuran; under Ar atm. to soln. (Ir(=C(t-Bu)P(Cy))(CO)(PPh3)2) in THF at -78°C soln. (PhHg)OTf in THF was added, allowed to warm slowly to room temp. and stirred 18 h; volatiles were removed in vacuo, residue was extd. with toluene and cooled to -30°C; elem. anal.;
DOI:10.1021/ic048532u