[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

Base Information

Chemical Name:[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]
CAS No.:1232440-04-8
Molecular Formula:C₂₅H₄₅P₃RuS₂
Molecular Weight:603.756
Hs Code.:

Synonyms:

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Chemical Property of [Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

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Technology Process of [Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

There total 3 articles about [Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 118-72-9
2,6-dimethylbenzene-1-thiol

: 868257-99-2
cis-[Ru(SC6H3(CH2-2)(Me-6)-κ2S,C)(trimethylphosphine)4]

: 1232440-04-8
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

: 1232440-16-2
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

Guidance literature:: In methanol; byproducts: trimethylphosphine; (Ar or N2); using Schlenk techniques; treatment of Ru(PMe3)3(SC6H3Me2)2 with 2,6-dimethylbenzenethiol in methanol at room temp. for 15 h;
DOI:10.1021/om100249s

Reference yield: 57.0%

: 118-72-9
2,6-dimethylbenzene-1-thiol

: 868257-99-2
cis-[Ru(SC6H3(CH2-2)(Me-6)-κ2S,C)(trimethylphosphine)4]

: 1232440-04-8
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

Guidance literature:: In acetone; byproducts: trimethylphosphine; (Ar or N2); using Schlenk techniques; addn. of acetone to Ru(PMe3)4(SC6H3(CH3)CH2), addn. of 2,6-dimethylbenzenethiol (15 equiv.) by hypodermic syringe, stirring for 30 min at room temp.; removal of all volatiles under vac., recrystn. from toluene;
DOI:10.1021/om100249s

Reference yield: 17.0%

: 71936-64-6,83247-97-6,96615-09-7
cis-{RuCl₂(PMe₃)4}

: 7732-18-5
water

: 2,6-dimethylthiophenol potassium salt

: 868257-99-2
cis-[Ru(SC6H3(CH2-2)(Me-6)-κ2S,C)(trimethylphosphine)4]

: 1232440-04-8
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

: 1232440-18-4
cis,mer-[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3(H₂O)]

Guidance literature:: In 1,2-dimethoxyethane; byproducts: KCl, trimethylphosphine; (Ar or N2); using Schlenk techniques; treatment of trans-RuCl2(PMe3)4 with potassium salt of 2,6-dimethylbenzenthiol in DME at 50°C for 3ds; removal of all volatile matters, extn. with C6D6 and 1,4-dioxane, crystn.; elem. anal.;
DOI:10.1021/om100249s