[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

Base Information

Chemical Name:[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]
CAS No.:1232440-16-2
Molecular Formula:C₂₈H₅₄P₄RuS₂
Molecular Weight:679.834
Hs Code.:

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Chemical Property of [Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

Chemical Property:

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Technology Process of [Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

There total 3 articles about [Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 118-72-9
2,6-dimethylbenzene-1-thiol

: 868257-99-2
cis-[Ru(SC6H3(CH2-2)(Me-6)-κ2S,C)(trimethylphosphine)4]

: 1232440-04-8
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

: 1232440-16-2
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

Guidance literature:: In methanol; byproducts: trimethylphosphine; (Ar or N2); using Schlenk techniques; treatment of Ru(PMe3)3(SC6H3Me2)2 with 2,6-dimethylbenzenethiol in methanol at room temp. for 15 h;
DOI:10.1021/om100249s

Reference yield:

: 1232440-04-8
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

: 594-09-2
trimethylphosphane

: 868257-99-2
cis-[Ru(SC6H3(CH2-2)(Me-6)-κ2S,C)(trimethylphosphine)4]

: 1232440-16-2
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

Guidance literature:: With P(OPh)3; triphenylmethane; In chloroform-d1; (Ar or N2); placing of Ru(SC6H3Me2)2(PMe3)3 and sealed ampule with P(OPh)3 in C6D6 as standart in NMR tube; introduction of CDCl3 by vac. distn., addn. of CHPh3 as standart, addn. of PMe3 by hypodermic syringe, monitoring by NMR at 30°C for 1.5 h;
DOI:10.1021/om100249s

Reference yield:

: 1232440-04-8
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)3]

: 594-09-2
trimethylphosphane

: 1232440-16-2
[Ru(bis(2,6-dimethylbenzenethiolato))(trimethylphosphine)4]

Guidance literature:: In d⁽⁴⁾-methanol; (Ar or N2); using Schlenk techniques; placing of Ru(PMe3)3(SC6H3Me2)2 inNMR tube, introduction of CD3OD by hypodermic syringe, addn. of PMe3 by hypodermic syringe, monitoring by NMR at 30°C for 20 min;
DOI:10.1021/om100249s