Tert-butyl (2R)-2-aminopent-4-enoate

Base Information

Chemical Name:Tert-butyl (2R)-2-aminopent-4-enoate
CAS No.:199588-89-1
Molecular Formula:C9H17NO2
Molecular Weight:171.2368
Hs Code.:2922499990
DSSTox Substance ID:DTXSID30455347
Nikkaji Number:J922.085B
Wikidata:Q82277307
Mol file:199588-89-1.mol

Synonyms:199588-89-1;TERT-BUTYL (2R)-2-AMINOPENT-4-ENOATE;(R)-2-AMINO-4-PENTENOIC ACID T-BUTYL ESTER;(R)-2-AMINO-4-PENTENOIC ACID TERT-BUTYL ESTER;4-Pentenoic acid, 2-amino-, 1,1-dimethylethyl ester, (2R)-;DTXSID30455347;FFDXLHHMGNXXAG-SSDOTTSWSA-N;tert-butyl (R)-aminopent-4-enoate;AKOS006284076;AKOS015841400;EN300-6505102

Suppliers and Price of Tert-butyl (2R)-2-aminopent-4-enoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(R)-2-AMINO-4-PENTENOIC ACID TERT-BUTYL ESTER 95.00%
5MG
$ 505.67

Total 10 raw suppliers

Chemical Property of Tert-butyl (2R)-2-aminopent-4-enoate

Chemical Property:

Boiling Point:193.547 °C at 760 mmHg
Flash Point:64.843 °C
PSA：52.32000
Density:0.953 g/cm3
LogP:1.93180
XLogP3:1.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:171.125928785
Heavy Atom Count:12
Complexity:170

Purity/Quality:

99% ^*data from raw suppliers

(R)-2-AMINO-4-PENTENOIC ACID TERT-BUTYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)OC(=O)C(CC=C)N
Isomeric SMILES:CC(C)(C)OC(=O)[C@@H](CC=C)N

Technology Process of Tert-butyl (2R)-2-aminopent-4-enoate

There total 22 articles about Tert-butyl (2R)-2-aminopent-4-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: (S)-2-[(1S,4R)-1-(tert-Butylsulfamoyl-methyl)-7,7-dimethyl-bicyclo[2.2.1]hept-(2E)-ylideneamino]-pent-4-enoic acid tert-butyl ester

: 163210-82-0,199588-89-1
(S)-2-allylglycine tert-butyl ester

Guidance literature:: With sodium hydroxide; hydroxylamine hydrochloride; acetic acid; In methanol; chloroform; at 25 ℃; for 24h;
DOI:10.1016/S0040-4020(97)00372-4

Reference yield: 89.0%

: 540-88-5
acetic acid tert-butyl ester

: (2S)-2-aminopent-4-enoic acid hydrochloride

: 163210-82-0,199588-89-1
(S)-2-allylglycine tert-butyl ester

Guidance literature:: With perchloric acid; at 20 ℃; for 24h; Inert atmosphere;
DOI:10.1002/chem.202004004

Reference yield: 78.0%

: 98946-18-0
tert-Butyl 2,2,2-trichloroacetimidate

: 146549-21-5
2-(9H-fluoren-9-ylmethoxycarbonylamino)-pent-4-enoic acid

: 163210-82-0,199588-89-1
(S)-2-allylglycine tert-butyl ester

Guidance literature:: tert-Butyl 2,2,2-trichloroacetimidate; 2-(9H-fluoren-9-ylmethoxycarbonylamino)-pent-4-enoic acid; In dichloromethane; at 20 ℃; for 72h;

With diethylamine; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1021/acs.orglett.1c03532