((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene

Base Information

• Chemical Name: ((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene
• CAS No.: 86838-50-8
• Molecular Formula: C₂₄H₄₀O
• Molecular Weight: 344.581
• Mol file: 86838-50-8.mol

Synonyms:

Chemical Property of ((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene

There total 12 articles about ((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl bromide (100-39-0) → ((S)-1-Pent-4-enyl-dodecyloxymethyl)-benzene (86838-50-8,86838-52-0)

Guidance literature:

Multi-step reaction with 6 steps

1: 90 percent / NaH / dimethylformamide

2: 50percent acetic acid / 1 h / 70 °C

3: HIO₄ / tetrahydrofuran / Ambient temperature

4: NaBH₄ / methanol

5: 95 percent / pyridine / Ambient temperature

6: Li₂CuCl₄ / tetrahydrofuran

With pyridine; sodium tetrahydroborate; dilithium tetrachlorocuprate; sodium hydride; acetic acid; periodic acid; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;

DOI:10.1016/S0040-4039(00)81833-X

Reference yield:

benzyl bromide (100-39-0) → ((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene (86838-50-8,86838-52-0)

Guidance literature:

Multi-step reaction with 6 steps

1: 90 percent / NaH / dimethylformamide

2: 50percent acetic acid / 1 h / 70 °C

3: HIO₄ / tetrahydrofuran / Ambient temperature

4: NaBH₄ / methanol

5: 95 percent / pyridine / Ambient temperature

6: Li₂CuCl₄ / tetrahydrofuran

With pyridine; sodium tetrahydroborate; dilithium tetrachlorocuprate; sodium hydride; acetic acid; periodic acid; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;

DOI:10.1016/S0040-4039(00)81833-X

Reference yield:

(2S,3S,4S)-4-Benzyloxy-non-8-ene-2,3-diol (86853-11-4) → ((R)-1-Pent-4-enyl-dodecyloxymethyl)-benzene (86838-50-8,86838-52-0)

Guidance literature:

Multi-step reaction with 4 steps

1: HIO₄ / tetrahydrofuran / Ambient temperature

2: NaBH₄ / methanol

3: 95 percent / pyridine / Ambient temperature

4: Li₂CuCl₄ / tetrahydrofuran

With pyridine; sodium tetrahydroborate; dilithium tetrachlorocuprate; periodic acid; In tetrahydrofuran; methanol;

DOI:10.1016/S0040-4039(00)81833-X

upstream raw materials:

n-decyl magnesium bromide

Toluene-4-sulfonic acid (R)-2-benzyloxy-hept-6-enyl ester

benzyl bromide

(R)-2-(benzyloxy)hept-6-en-1-ol

Downstream raw materials:

(R)-5-Benzyloxy-hexadecanoic acid

(S)-5-Benzyloxy-hexadecanoic acid