3-(4-bromophenyl)-N-phenylcarbazole

Base Information

• Chemical Name: 3-(4-bromophenyl)-N-phenylcarbazole
• CAS No.: 1028647-93-9
• Molecular Formula: C24H16BrN
• Molecular Weight: 398.302
• Hs Code.: 2933990090
• Mol file: 1028647-93-9.mol

Synonyms:3-(4-bromophenyl)-N-phenyl-9H-Carbazole;

Chemical Property of 3-(4-bromophenyl)-N-phenylcarbazole

Chemical Property:

• Melting Point: 136.0 to 140.0 °C
• Boiling Point: 560.518 °C at 760 mmHg
• Flash Point: 292.791 °C
• PSA: 4.93000
• Density: 1.329 g/cm³
• LogP: 7.21320
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: slightly sol. in Toluene

Purity/Quality:

99%Min ^*data from raw suppliers

3-(4-Bromophenyl)-9-phenyl-9H-carbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 3-(4-BROMOPHENYL)-9-PHENYL-9H-CARBAZOLE is a useful research chemical.

Technology Process of 3-(4-bromophenyl)-N-phenylcarbazole

There total 21 articles about 3-(4-bromophenyl)-N-phenylcarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

N-phenyl-9H-carbazol-3-boronic acid (854952-58-2) + 1,4-bromoiodobenzene (589-87-7) → 3-(4-bromophenyl)-9-phenyl-9H-carbazole (1028647-93-9)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; water; at 60 ℃; for 3h;

Reference yield: 85.6%

N-phenyl-9H-carbazol-3-boronic acid (854952-58-2) + 1.4-dibromobenzene (106-37-6) → 3-(4-bromophenyl)-9-phenyl-9H-carbazole (1028647-93-9)

Guidance literature:

With tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate; In toluene; at 110 ℃; for 8h; Inert atmosphere;

Reference yield: 81.0%

1,4-bromoiodobenzene (589-87-7) + 9-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolane-2-yl)-9H-carbazole (1126522-69-7) → 3-(4-bromophenyl)-9-phenyl-9H-carbazole (1028647-93-9)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; toluene; for 12h; Inert atmosphere; Reflux;

upstream raw materials:

4-Bromophenylboronic acid

3-iodo-9-phenyl-9H-carbazole

N-phenyl-9H-carbazol-3-boronic acid

1,4-bromoiodobenzene

Downstream raw materials:

(4-(1-naphthyl)-phenyl)-(4-(9-phenyl-9H-carbazol-3-yl)-phenyl)-phenyl-amine

(biphenyl-4-yl)(phenyl)[4'-(9-phenyl-9H-carbazol-3-yl)biphenyl-4-yl]amine

bis(biphenyl-4-yl)[4'-(9-phenyl-9H-carbazol-3-yl)biphenyl-4-yl]amine

4-[4-(1-naphthyl)phenyl]-4'-(9-phenyl-9H-carbazol-3-yl)diphenylamine

Refernces

• 1、 -. "Organic compound, and organic electroluminescent device and display device comprising organic compound (by machine translation)". Paragraph 0127-0128; 0134-0135. . Retrieved 2020/06/17.
• 2、 -. "COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING THE SAME, AND A ELECTRONIC DEVICE THEREOF". Paragraph 0272; 0286-0295. . Retrieved 2020/05/30.