Re₂Cl₃((C₆H₅)2PCH₂P(C₆H₅)2)2((NCC₂H₄)3P)2⁽¹⁺⁾*PF₆^(1-)=Re₂Cl₃(P(C₆H₅)2CH₂P(C₆H₅)2)2((NCC₂H₄)3P)2PF₆

Base Information

• Chemical Name: Re₂Cl₃((C₆H₅)2PCH₂P(C₆H₅)2)2((NCC₂H₄)3P)2⁽¹⁺⁾*PF₆^(1-)=Re₂Cl₃(P(C₆H₅)2CH₂P(C₆H₅)2)2((NCC₂H₄)3P)2PF₆
• CAS No.: 294213-49-3
• Molecular Formula: C₆₈H₆₈Cl₃N₆P₆Re₂*F₆P
• Molecular Weight: 1778.91

Synonyms:

Chemical Property of Re₂Cl₃((C₆H₅)2PCH₂P(C₆H₅)2)2((NCC₂H₄)3P)2⁽¹⁺⁾*PF₆^(1-)=Re₂Cl₃(P(C₆H₅)2CH₂P(C₆H₅)2)2((NCC₂H₄)3P)2PF₆

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Technology Process of Re₂Cl₃((C₆H₅)2PCH₂P(C₆H₅)2)2((NCC₂H₄)3P)2⁽¹⁺⁾*PF₆^(1-)=Re₂Cl₃(P(C₆H₅)2CH₂P(C₆H₅)2)2((NCC₂H₄)3P)2PF₆

There total 1 articles about Re₂Cl₃((C₆H₅)2PCH₂P(C₆H₅)2)2((NCC₂H₄)3P)2⁽¹⁺⁾*PF₆^(1-)=Re₂Cl₃(P(C₆H₅)2CH₂P(C₆H₅)2)2((NCC₂H₄)3P)2PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

potassium hexafluorophosphate (17084-13-8) + [Re2Cl4(μ-bis(diphenylphosphino)methane)2] (58298-10-5) + tris(2-cyanoethyl)phosphine (4023-53-4) → Re2Cl3((C6H5)2PCH2P(C6H5)2)2((NCC2H4)3P)2(1+)*PF6(1-)=Re2Cl3(P(C6H5)2CH2P(C6H5)2)2((NCC2H4)3P)2PF6 (294213-49-3)

Guidance literature:

In acetone; mixt. of Re-complex, KPF6 and ligand in acetone was stirred at room temp. for 2 h under N2; vol. was reduced by vac. evaporator, filtered, filtrate was treated with Et2O, stirred for 30 min, extracted into CH2Cl2, vol. of extract was reduced, Et2O was added; elem. anal.;

DOI:10.1016/S0020-1693(00)00127-4

Reference yield: 80.0%

nitrosyl hexafluorophosphate (16921-91-8) + Re2Cl3((C6H5)2PCH2P(C6H5)2)2((NCC2H4)3P)2(1+)*PF6(1-)=Re2Cl3(P(C6H5)2CH2P(C6H5)2)2((NCC2H4)3P)2PF6 (294213-49-3) → Re2Cl3((C6H5)2PCH2P(C6H5)2)2((NCC2H4)3P)2(2+)*2PF6(1-)=Re2Cl3(P(C6H5)2CH2P(C6H5)2)2((NCC2H4)3P)2(PF6)2

Guidance literature:

In dichloromethane; Re-complex and NOPF6 in CH2Cl2 was reacted at room temp. for 30 min under N2; filtered, filtrate was reduced in vol., Et2O was added;

DOI:10.1016/S0020-1693(00)00127-4

upstream raw materials:

potassium hexafluorophosphate

[Re2Cl4(μ-bis(diphenylphosphino)methane)2]

tris(2-cyanoethyl)phosphine

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