[(η5-C5Me5)Ru(N(Ph2PS)2)Cl]

Base Information

• Chemical Name: [(η5-C5Me5)Ru(N(Ph2PS)2)Cl]
• CAS No.: 879640-76-3
• Molecular Formula: C₃₄H₃₅ClNP₂RuS₂
• Molecular Weight: 720.261
• Mol file: 879640-76-3.mol

Synonyms:

Chemical Property of [(η5-C5Me5)Ru(N(Ph2PS)2)Cl]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(η5-C5Me5)Ru(N(Ph2PS)2)Cl]

There total 1 articles about [(η5-C5Me5)Ru(N(Ph2PS)2)Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

pentamethylcyclopentadienyl-ruthenium(III) chloride + potassium tetraphenyldithioimidodiphosphinate (6588-06-3) → [(η5-C5Me5)Ru(N(Ph2PS)2)Cl] (879640-76-3)

Guidance literature:

In tetrahydrofuran; under N2, Schlenk techniques; mixt. of Ru compd. and dithioimidodiphosphinate in THF stirred at room temp. for 1 h; evapn., residue washed with Et2O, recrystn. from CH2Cl2/hexane at room temp.; elem. anal.;

DOI:10.1016/j.ica.2005.04.031

Reference yield: 55.0%

[(η5-C5Me5)Ru(N(Ph2PS)2)Cl] (879640-76-3) + water (7732-18-5) → [(η5-C5Me5)Ru(N(Ph2PS)2)]*H2O

Guidance literature:

With LiB(CH₂CH₃)3H; In tetrahydrofuran; under N2, Schlenk techniques; soln. of LiBEt3H in in THF added to soln. of Ru complex in THF at -78°C, warming to room temp., stirring atroom temp. for 2 h; evapn., oily residue extd. with hexane, extract concd., stored at -10°C; elem. anal.;

DOI:10.1016/j.ica.2005.04.031

Reference yield:

[(η5-C5Me5)Ru(N(Ph2PS)2)Cl] (879640-76-3) → [(η5-C5Me5)Ru(N(Ph2PS)2)Cl](1+)

Guidance literature:

With silver triflate or iodine; In not given;

DOI:10.1016/j.ica.2005.04.031

upstream raw materials:

potassium tetraphenyldithioimidodiphosphinate