Technology Process of 15-Benzyl-9,14-dihydro-10,11,12,13-tetramethyl-9,14-iminobenzotriphenylen
There total 4 articles about 15-Benzyl-9,14-dihydro-10,11,12,13-tetramethyl-9,14-iminobenzotriphenylen which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 5 steps
1: N-bromosuccinimide, azobis isobutyronitrile
2: 76 percent / ethyl diisopropylamine / CH2Cl2 / 5 h / Heating
3: 78 percent / 60percent H2O2 / methanol; CHCl3 / 72 h / Ambient temperature; 1.) 3d, r.t., 2.) 1d, r.t.
4: 68 percent / Et3N, acetic anhydride / CHCl3 / 1.) 15 min, 0 deg C, 2.) 3.5h, r.t.
5: 41 percent / CH3Li / tetrahydrofuran; diethyl ether / 12 h / -130 - 25 °C
With
N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); methyllithium; dihydrogen peroxide; acetic anhydride; triethylamine; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform;
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 76 percent / ethyl diisopropylamine / CH2Cl2 / 5 h / Heating
2: 78 percent / 60percent H2O2 / methanol; CHCl3 / 72 h / Ambient temperature; 1.) 3d, r.t., 2.) 1d, r.t.
3: 68 percent / Et3N, acetic anhydride / CHCl3 / 1.) 15 min, 0 deg C, 2.) 3.5h, r.t.
4: 41 percent / CH3Li / tetrahydrofuran; diethyl ether / 12 h / -130 - 25 °C
With
methyllithium; dihydrogen peroxide; acetic anhydride; triethylamine; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; methanol; diethyl ether; dichloromethane; chloroform;
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 78 percent / 60percent H2O2 / methanol; CHCl3 / 72 h / Ambient temperature; 1.) 3d, r.t., 2.) 1d, r.t.
2: 68 percent / Et3N, acetic anhydride / CHCl3 / 1.) 15 min, 0 deg C, 2.) 3.5h, r.t.
3: 41 percent / CH3Li / tetrahydrofuran; diethyl ether / 12 h / -130 - 25 °C
With
methyllithium; dihydrogen peroxide; acetic anhydride; triethylamine;
In
tetrahydrofuran; methanol; diethyl ether; chloroform;
