57743-47-2

Upstream product

• 604-83-1 9,10-dimethylphenanthrene 
• 7251-51-6 9,10-dimethyl-9,10-dihydrophenanthrene-9,10-diol 
• 18442-29-0 2,2′-bis(ethynyl)-1,1′-biphenyl 
• 766-46-1 2-bromo-1-ethynylbenzene 
• 101110-13-8 phenanthrene-9,10-diyldimethanol 
• 15810-16-9 dimethyl 9,10-phenanthrenedicarboxylic acid 
• 38274-16-7 2-bromo-1-(trimethylsilylethynyl)benzene 
• 18238-34-1 2,2′-bis[(trimethylsilyl)ethynyl]biphenyl 
• 25148-25-8 9-chloromethyl-10-methyl-phenanthrene 
• 38274-14-5 2,2'-bis-(bromomethyl)-1,1'-biphenyl 
• 34919-47-6 2,2'-divinylbiphenyl 

Downstream Products

• 33537-23-4 9,10-Dimethylen-9,10-dihydro-phenanthren 
• 110028-22-3 13-Benzyl-1,4-dihydro-1,4-iminotriphenylen-2,3-dicarbonsaeure-dimethylester 
• 110028-25-6 15-Benzyl-9,14-dihydro-10,11,12,13-tetramethyl-9,14-iminobenzotriphenylen 
• 110028-18-7 2-Benzyl-2,3-dihydro-1H-dibenzisoindol-N-oxid 
• 110028-20-1 2-Benzyl-2H-dibenzisoindol 
• 110028-16-5 2-Benzyl-2,3-dihydro-1H-dibenzisoindol 

Relevant academic research and scientific papers

Synthesis and Characterization of 1-Hydroxy-4,5-arene-Fused Tropylium Derivatives

The properties of 1-hydroxy-4,5-arene-fused tropyliums were assessed based on experimental and theoretical investigations. An X-ray crystallographic analysis revealed a decrease of bond alternation in the seven-membered ring of 1-hydroxy-4,5-benzotropylium derivatives compared with that of the parent 4,5-benzotropones, which is indicative of an increase in aromaticity upon protonation. NICS and AICD calculations also supported the increased aromaticity of 1-hydroxy-4,5-arene-fused tropylium. The pKa values for a series of 1-hydroxy-4,5-arene-fused tropylium derivatives were also determined.

Synthesis and characterization of phenanthrene-substituted fullerene derivatives as electron acceptors for P3HT-based polymer solar cells

9,10-Bis(bromomethyl)phenanthrene reacted with fullerenes via a Diels-Alder reaction to give phenanthrene-substituted fullerene mono-adducts (PCMA) and bis-adducts (PCBA) as electron acceptors for organic photovoltaic cells (OPVs). The syntheses of the fullerene derivatives were confirmed by 1H 13C NMR spectroscopy and MALDI-TOF mass spectrometry. PCMA and PCBA showed better light absorption in the UV-visible region than PC61BM. Their electrochemical properties were measured using cyclic voltammetry. Accordingly, the lowest unoccupied molecular orbital (LUMO) energy levels of PCMA and PCBA were -3.66 and -3.57 eV, respectively. Photovoltaic cells were fabricated with a ITO/PEDOT:PSS/poly(3-hexylthiophene)( P3HT):acceptor/LiF/Al configuration, where P3HT and PCBA are the electron donors and acceptors, respectively. The polymer solar cell fabricated using the P3HT:PCBA active layer showed a maximum power conversion efficiency of 0.71%.

Synthesis of linearly and angularly fused indane-based constrained α-amino acid derivatives

The benzocyclobutene-based α-amino acid derivative, ethyl 5-acetamido-2,4,5,6-tetrahydro-1H-cyclobuta[f]indene-5-carboxylate is synthesized via coupling of a benzocyclobutene-derived dibromide with ethyl isocyanoacetate as the key step, followed by hydrolysis and subsequent acetylation. This methodology is generalized in order to prepare various linearly and angularly fused indane-based α-amino acid derivatives. Georg Thieme Verlag Stuttgart - New York.

Synthesis of Benzophenanthrocyclooctene

A phenanthrene-fused cyclooctatetraene, namely benzophenanthrocyclooctene has been synthesized by employing the "Reich-Paquette" procedure.

Studies on the Chemistry of Isoindoles and Isoindolenines, XXVII. - 2-Alkyl-2H-dibenzisoindoles; Synthesis, Properties, Reactions

The tetracyclic hetarenes 6 are easily accessible via N-oxide route starting with 9,10-bis(bromomethyl)phenanthrene (3) in a three-step procedure.The twofold annelation reduces the diene reactivity of the central 2H-isoindole system.Cycloaddition occurs a